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Synthesis and Sorption Study of Vinyl-Addition Polynorbornene with Dimethylanthracene Substituent

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Norbornene containing a substituent with the 9,10-dihydroanthracene moiety and two methyl groups was synthesized. The conditions of its vinyl-addition polymerization ensuring the formation of the high-molecular-weight product (Mw > 5 × 105) in a high yield (>70%) were determined. The polymer synthesized was characterized by NMR spectroscopy, X-ray diffraction analysis, and thermogravimetric analysis. The sorption properties of the polymer, including their variation with time, were studied by low-temperature nitrogen adsorption–desorption. The polymer has the specific surface area of up to 550 m2 g–1, contains micro- and mesopores, and is prone to physical aging.

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Funding

The study was financially supported by the Russian Science Foundation (project no. 22-79-10054).

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    M. A. Zotkin, D. A. Alentiev & M. V. Bermeshev

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    N. N. Gavrilova

Authors
  1. M. A. Zotkin
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  2. D. A. Alentiev
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  3. N. N. Gavrilova
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  4. M. V. Bermeshev
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Corresponding author

Correspondence to D. A. Alentiev.

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The authors declare that they have no conflict of interest.

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Translated from Zhurnal Prikladnoi Khimii, Nos. 11–12, pp. 1468–1475, August, 2022 https://doi.org/10.31857/S0044461822110111

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Zotkin, M.A., Alentiev, D.A., Gavrilova, N.N. et al. Synthesis and Sorption Study of Vinyl-Addition Polynorbornene with Dimethylanthracene Substituent. Russ J Appl Chem 95, 1809–1816 (2022). https://doi.org/10.1134/S1070427222120072

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  • DOI: https://doi.org/10.1134/S1070427222120072

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