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Hydrodeoxygenation of Bio-oil Components Containing a Guaiacol Fragment in the Presence of a Ruthenium-Suppoting Mesoporous Aluminosilicate Catalyst

  • Catalysis
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Abstract

A ruthenium catalyst based on hexagonal mesoporous silica modified with aluminum (Al-HMS structural type) of a Si/Al ratio equal to 10 was studied in the hydrodeoxygenation reaction of bio-oil components containing a guaiacol fragment. The catalyst was tested in the hydrodeoxygenation of guaiacol, methoxyguaiacol, formylguaiacol, and propylguaiacol in the presence of water at a hydrogen pressure of 6.0 MPa and a temperature of 250°C. The effect of the substrate structure on the conversion and selectivity of hydrotransformation towards fully hydrogenated and deoxygenated products is shown. The effect of temperature in the range of 210–290°C on the conversion and distribution of guaiacol hydrodeoxygenation products at various hydrogen pressures (2.5 and 6.0 MPa) is demonstrated. Experiments were carried out on the hydrodeoxygenation of guaiacol in a mixture with water, n-dodecane, and methanol at a hydrogen pressure of 6.0 MPa and a temperature of 250°C. The effect of the model mixture composition on the conversion and distribution of guaiacol hydrodeoxygenation products is shown.

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Funding

The study was supported by the Russian Science Foundation grant no. 22-79-00118.

https://rscf.ru/project/22-79-00118/

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Authors and Affiliations

  1. Moscow State University, 119991, Moscow, Russia

    E. A. Roldugina, S. V. Kardashev, A. L. Maksimov & E. A. Karakhanov

  2. Topchiev Institute of Petroleum Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maksimov

Authors
  1. E. A. Roldugina
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  2. S. V. Kardashev
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  3. A. L. Maksimov
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  4. E. A. Karakhanov
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Contributions

E.A. Karakhanov proposed the concept of the study; E.A. Roldugina conducted catalytic experiments and is the main author of the manuscript text; S.V. Kardashev analyzed the products of catalytic reactions; A.L. Maksimov contributed to the interpretation of the catalysis results.

Corresponding author

Correspondence to E. A. Roldugina.

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A.L. Maksimov is the editor-in-chief of the Journal of Applied Chemistry. The remaining co-authors declare no conflict of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, Nos. 11–12, pp. 1389–1399, August, 2022 https://doi.org/10.31857/S0044461822110044

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Roldugina, E.A., Kardashev, S.V., Maksimov, A.L. et al. Hydrodeoxygenation of Bio-oil Components Containing a Guaiacol Fragment in the Presence of a Ruthenium-Suppoting Mesoporous Aluminosilicate Catalyst. Russ J Appl Chem 95, 1756–1766 (2022). https://doi.org/10.1134/S1070427222120023

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