Skip to main content
SpringerLink
Log in

Stereoregularity of Polyisoprene Obtained in the Presence of a Catalyst Based on Gadolinium Chloride

  • Catalysis
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Reliable NMR determination of the stereoisomeric composition of polyisoprene obtained in the presence of a catalyst based on a solvation complex of gadolinium chloride with isopropanol, activated with triisobutylaluminum, is possible only after thorough removal of traces of gadolinium compounds, which are strong relaxants in magnetic resonance imaging. In determination of the stereoisomeric composition of polyisoprene by Fourier IR spectroscopy, more reliable results are reached when plotting a separate baseline for each absorption band.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Scheme 1.
Fig. 4.
Fig. 5.
Fig. 6.

REFERENCES

  1. Huang, Z., Wang, S., Zhu, X., Yuan, Q., Zhou, S., Mu, X., and Wang, H., Chin. J. Chem., 2021, vol. 39, pp. 3360–3368. https://doi.org/10.1002/cjoc.202100539

    Article  CAS  Google Scholar 

  2. Nifant’ev, I., Tavtorkin, A., Korchagina, S., Gavrilenko, I., Glebova, N., Kostitsyna, N., Yakovlev, V., Bondarenko, G., and Filatova, M., Appl. Catal. A, 2014, vol. 478, pp. 219–227. https://doi.org/10.1016/j.apcata.2014.04.007

    Article  CAS  Google Scholar 

  3. Tereshchenko, K., Ulitin, N., Shiyan, D., Al’metova, G., Zakharova, E., Nasyrov, I., and Zakharov, V., Russ. J. Phys. Chem. B, 2019, vol. 13, no. 1, pp. 170–176. https://doi.org/10.1134/S1990793119010299

    Article  CAS  Google Scholar 

  4. Zhang, S., Wu, N., and Wu, Y.-X., Chin. J. Polym. Sci., 2020, vol. 38, no. 12, pp. 1305–1312. https://doi.org/10.1007/s10118-020-2460-4

    Article  CAS  Google Scholar 

  5. Jia, T., Xu, S., Huang, L., and Gao, W., Polyhedron, 2018, vol. 145. no. 1, pp. 182–190. https://doi.org/10.1016/j.poly.2018.02.010

    Article  CAS  Google Scholar 

  6. Lv, K. and Cui, D., Organometallics, 2010, vol. 29, no. 13, pp. 2987–2993. https://doi.org/10.1021/om1002039

    Article  CAS  Google Scholar 

  7. Shen, Z., Song, X., Xiao, S., Yang, J., and Kan, X., J. Appl. Polym. Sci., 1983, vol. 28, no. 5, pp. 1585–1597. https://doi.org/10.1002/app.1983.070280504

    Article  CAS  Google Scholar 

  8. Stiazhkin, D., Plotnikova, N., Yanborisov, V., Zaharova, E., Mingaleev, V., Kolesov, S., and Zaharov, V., Kinet. Catal., 2022, vol. 63, pp. 480–485. https://doi.org/10.1134/S0023158422050123

    Article  CAS  Google Scholar 

  9. Doddrell, D., Pegg, D., and Bendall, M., J. Magn. Reson., 1982, vol. 48, no. 2, pp. 323–327. https://doi.org/10.1016/0022-2364(82)90286-4

    Article  CAS  Google Scholar 

  10. Davis, A., Keeler, J., Laue, E., and Moskau, D., J. Magn. Reson., 1992, vol. 98, no. 1, pp. 207–216. https://doi.org/10.1016/0022-2364(92)90126-R

    Article  CAS  Google Scholar 

  11. Hurd, R. and John, B., J. Magn. Reson., 1991, vol. 91, no. 3, pp. 648–653. https://doi.org/10.1016/0022-2364(91)90395-A

    Article  CAS  Google Scholar 

  12. Willker, W., Leibfritz, D., Kerssebaum, R., and Bermel, W., Magn. Reson. Chem., 1993, vol. 31, no. 3, pp. 287–292. https://doi.org/10.1002/mrc.1260310315

    Article  CAS  Google Scholar 

  13. Jeener, J., Meier, B., Bachmann, P., and Ernst, R., J. Chem. Phys., 1979, vol. 71, no. 11, pp. 4546–4553. https://doi.org/10.1063/1.438208

    Article  CAS  Google Scholar 

  14. Isakova, N.A., Belova, G.A., and Fikhtengol’ts, V.S., Kontrol’ proizvodstva sinteticheskikh kauchukov (Control of Synthetic Rubber Production), Leningrad: Khimiya, 1980, pp. 206–210.

    Google Scholar 

  15. Koenig, S. and Brown, R., Prog. Nucl. Magn. Reson. Spectrosc., 1990, vol. 22, pp. 487–567. https://doi.org/10.1016/0079-6565(90)80008-6

    Article  CAS  Google Scholar 

  16. Mulder, F., TeNri, L., and Luchinat, C., Angew. Chem. Int. Ed., 2019, vol. 131, no. 43, pp. 15427–15430. https://doi.org/10.1002/ange.201908006

    Article  Google Scholar 

  17. Honrao, Ch., Teissier, N., Zhang, B., Powers, R., and O’Day, E., Molecules, 2021, vol. 26, no. 17, pp. 5115–5130. https://doi.org/10.3390/molecules26175115

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  18. Makhiyanov, N., Polym. Sci., Ser. A, 2017, vol. 59, no. 2, pp. 269–279. https://doi.org/10.1134/S0965545X17020067

    Article  CAS  Google Scholar 

  19. Lye, C., Aun, Y., and Huat, O., Res. J. Nanosci. Eng., 2019, vol. 3, no. 3, pp. 1–8.

    Google Scholar 

  20. Zhang, S., Wu, N., and Wu, Y-X., Chin. J. Polym. Sci., 2020, vol. 38, pp. 1305–1312. https://doi.org/10.1007/s10118-020-2460-4

    Article  CAS  Google Scholar 

  21. Hu, Y., Zhang, C., Liu, X., Gao, K., Cao, Y., Zhang, C., and Zhang, X., J. Appl. Polym. Sci., 2014, vol. 131, no. 5, pp. 40153–40159. https://doi.org/10.1002/APP.40153

    Article  Google Scholar 

  22. Nallasamy, P. and Mohan, S., Arab. J. Sci. Eng., 2004, vol. 29, no. 14, pp. 17–26.

    CAS  Google Scholar 

  23. Arjunan, V., Subramanian, S., and Mohan, S., Spectrochim. Acta,Part A: Mol. Biomol. Spectrosc., 2001, vol. 57, pp. 2547–2554. https://doi.org/10.1016/S1386-1425(01)00426-7

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The analyses (measurements and calculations) were performed using the equipment of the Chemistry Center for Shared Use, Ufa Institute of Chemistry, Russian Academy of Sciences.

Funding

The study was financially supported within the framework of government assignment nos. 1021062311391-0-1.4.4 and FJWU-2020-0027.

Author information

Authors and Affiliations

  1. Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, 450054, Bashkortostan, Russia

    D. V. Styazhkin, N. M. Shishlov, A. N. Lobov & S. V. Kolesov

Authors
  1. D. V. Styazhkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. M. Shishlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Lobov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. V. Kolesov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. V. Styazhkin.

Ethics declarations

The authors declare that they have no conflict of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 10, pp. 1282–1292, October, 2022 https://doi.org/10.31857/S0044461822100073

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Styazhkin, D.V., Shishlov, N.M., Lobov, A.N. et al. Stereoregularity of Polyisoprene Obtained in the Presence of a Catalyst Based on Gadolinium Chloride. Russ J Appl Chem 95, 1573–1583 (2022). https://doi.org/10.1134/S1070427222100081

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427222100081

Keywords:

Search

Navigation