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Hydrogenation of Guaiacol on Nanoscale Supported Ruthenium Catalysts: Influence of Support Particle Size and the Presence of Bio-oil Oxygenates

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Abstract

Mesoporous nanospherical resorcinol-formaldehyde polymers NSMR-1 and NSMR-2 are synthesized. They are characterized by an average material particle size of 289 and 156 nm, respectively. Hybrid catalysts NSMR-Ru-1 and NSMR-Ru-2 were fabricated, which are Ru nanoparticles included in the structure of polymer supports NSMR-1 and NSMR-2. The catalysts were tested in the guaiacol hydrogenation at a temperature of 200°C and a hydrogen pressure of 5.0 MPa in an aqueous medium. It was found that the NSMR-Ru-2 catalyst, which is characterized by a smaller support particle size, exhibits a higher activity compared to the NSMR-Ru-1 catalyst. Experiments were carried out on the hydrogenation of guaiacol in a mixture with methanol, acetic acid, and furfural over the NSMR-Ru-2 catalyst. The influence of oxygenates on the conversion of guaiacol and the selectivity for its hydrogenation products was displayed.

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Funding

The study was supported by a grant from the Russian Science Foundation (project no. 22-79-10077).

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Authors and Affiliations

  1. Moscow State University, Faculty of Chemistry, 119991, Moscow, Russia

    M. P. Boronoev, I. I. Shakirov, E. A. Roldugina, Yu. S. Kardasheva, S. V. Kardashev, A. L. Maksimov & E. A. Karakhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maksimov

Authors
  1. M. P. Boronoev
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  2. I. I. Shakirov
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  3. E. A. Roldugina
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  4. Yu. S. Kardasheva
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  5. S. V. Kardashev
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  6. A. L. Maksimov
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  7. E. A. Karakhanov
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Corresponding author

Correspondence to M. P. Boronoev.

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Co-author A.L. Maksimov is the editor-in-chief of the Journal of Applied Chemistry. The remaining co-authors declare no conflicts of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 10, pp. 1263–1272, October, 2022 https://doi.org/10.31857/S004446182210005X

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Boronoev, M.P., Shakirov, I.I., Roldugina, E.A. et al. Hydrogenation of Guaiacol on Nanoscale Supported Ruthenium Catalysts: Influence of Support Particle Size and the Presence of Bio-oil Oxygenates. Russ J Appl Chem 95, 1555–1563 (2022). https://doi.org/10.1134/S1070427222100068

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