Abstract
The joint effect exerted on the hydrophobic properties of two-component polyurethane coatings by SiO2–NH2 particles prepared from tetraethoxysilane and 3-aminopropyltriethoxysilane using the sol–gel procedure and by an organosilicon block copolymer was studied. The structure and size distribution of particles were determined by Fourier IR spectroscopy, differential thermal analysis, and laser light scattering. Introduction of SiO2–NH2 particles leads to an increase in the roughness and change in topography of the polyurethane coating surface, which was proved by atomic force microscopy and scanning electron microscopy. Variation of the content of the organosilicon block copolymer influences the SiO2–NH2 particle-size distribution in the composite, the surface topography, and wetting of the coatings and allows preparation of highly hydrophobic polyurethane coatings with the contact angle and hysteresis of 166.2° and 11.9°, respectively.
REFERENCES
Somarathna, H.M.C.C., Raman, S.N., Mohotti, D., Mutalib, A.A., and Badri, K.H., Constr. Build. Mater., 2018, vol. 190, pp. 995–1014. https://doi.org/10.1016/j.conbuildmat.2018.09.166
Fihri, A., Bovero, E., Al-Shahrani, A., Al-Ghamdi, A., and Alabedi, G., Colloids Surf. A : Physicochem. Eng. Asp., 2017, vol. 520, pp. 378–390. https://doi.org/10.1016/j.colsurfa.2016.12.057
Luo, G., Jin, Z., Dong, Y., Huang, J., Zhang, R., Wang, J., and Zhang, L., Surf. Eng., 2016, vol. 34, no. 2, pp. 139–145. https://doi.org/10.1080/02670844.2016.1236068
Guo, J., Wang, C., Yu, H., and Li, X., Prog. Org. Coat., 2020, vol. 146, ID 105710. https://doi.org/10.1016/j.porgcoat.2020.105710
Ke, C., Li, Z., Zhang, C., Wu, X., Zhu, Z., and Jiang, Y., Coatings, 2021, vol. 11, no. 2, ID 174. https://doi.org/10.3390/coatings11020174
Voznyakovskii, A.P., Kudoyarova, V.K., Kudoyarov, M.F., and Patrova, M.Y., Phys. Solid State, 2017, vol. 59, no. 8, pp. 1656–1661. https://doi.org/10.1134/S1063783417080327
Shi, S., Yang, J., Liang, S., Li, M., Gan, Q., Xiao, K., and Hu, J., Sci. Total Environ., 2018, vol. 628, pp. 499–508. https://doi.org/10.1016/j.scitotenv.2018.02.091
Pavlenko, V.I., Cherkashina, N.I., and Demkina, L.N., IOP Conf. Ser. : Mater. Sci. Eng., 2018, vol. 327, no. 5, ID 052026. https://doi.org/10.1088/1757-899X/327/5/052026
Couble, J., Buniazet, Z., Loridant, S., and Bianchi, D., Langmuir, 2020, vol. 36, no. 45, pp. 13371–13382. https://doi.org/10.1021/acs.langmuir.0c01716
Erofeev, D.A. and Mashlyakovskii, L.N., Izv. Sankt-Peterb. Gos. Tekhnol. Inst. (Tekh. Univ.), 2022, no. 61, pp. 42–50. https://doi.org/10.36807/1998-9849-2022-61-87-44-50
Sui, T., Ding, M., Ji, C., Yan, S., Wei, J., Wang, A., Zhao, F., and Fei, J., Ceram. Int., 2018, vol. 44, no. 15, pp. 18438–18443. https://doi.org/10.1016/j.ceramint.2018.07.061
Giraldo, L.J., Giraldo, M.A., Llanos, S., Maya, G., Zabala, R.D., Nassar, N.N., and Cortés, F.B., J. Petrol. Sci. Eng., 2017, vol. 159, pp. 841–852. https://doi.org/10.1016/j.petrol.2017.10.009
Jalali Dil, E., Arjmand, M., Otero Navas, I., Sundararaj, U., and Favis, B.D., Macromolecules, 2020, vol. 53, no. 22, pp. 10267–10277. https://doi.org/10.1021/acs.macromol.0c01525
Darani, M.K., Bastani, S., Ghahari, M., Kardar, P., and Mohajerani, E., Prog. Org. Coat., 2018, vol. 122, pp. 263–269. https://doi.org/10.1016/j.porgcoat.2018.01.022
Erofeev, D.A., Mashlyakovskii, L.N., Khomko, E.V., and Litosov, G.E., Russ. J. Appl. Chem., 2021, vol. 94, no. 5, pp. 647–655. https://doi.org/10.1134/107042722105013X
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Translated from Zhurnal Prikladnoi Khimii, No. 10, pp. 1251–1262, October, 2022 https://doi.org/10.31857/S0044461822100048
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Erofeev, D.A., Mashlyakovskii, L.N. Highly Hydrophobic Polyurethane Coatings Modified with an Organosilicon Block Copolymer and Amino-Functionalized Nano/Microdispersed SiO2–NH2. Russ J Appl Chem 95, 1539–1549 (2022). https://doi.org/10.1134/S1070427222100044
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DOI: https://doi.org/10.1134/S1070427222100044