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Synthesis of Silver Particles in Micelles Stabilized by a Vinyl Acetate–N-Vinylpyrrolidone Block Copolymer

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The stabilizing effect exerted on silver particles in aqueous-organic media by a copolymer consisting of blocks of polyvinyl acetate prepared by controlled reversible addition–fragmentation chain-transfer radical polymerization and of poly-N-vinylpyrrolidone was studied. The micelles formed by the block copolymer can act as reactors for the synthesis of silver particles by reduction of the salt preliminary introduced into the micelles. The sizes of micelles based on silver sol particles and of metal particles after removing the polymer on a graphite support were determined. Conditions were found for preparing spherical silver particles no more than 100 nm in diameter with uniform particle size. The composites based on these systems and formed on the surface of thermally expanded graphite exhibit catalytic activity in oxidation of Pyrocatechol Violet dye.

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REFERENCES

  1. Sarkar, B. and Alexandridis, P., Prog. Polym. Sci., 2015, vol. 40, no. 1, pp. 33–62. https://doi.org/10.1016/j.progpolymsci.2014.10.009

    Article  CAS  Google Scholar 

  2. Tovstun, S.A. and Razumov, V.F., Russ. Chem. Rev., 2011, vol. 80, no. 10, pp. 953–969. https://doi.org/10.1070/RC2011v080n10ABEH004154

    Article  CAS  Google Scholar 

  3. Ostaeva, G.Yu., Bogdanov, A.G., and Papisov, I.M., Polym. Sci., Ser. B, 2006, vol. 48, nos. 3–4, pp. 101–103.

    Article  Google Scholar 

  4. Senchukova, A.S., Mikhailova, M.E., Lesov, A.A., Lebedeva, E.V., Podseval’nikova, A.N., and Tsvetkov, N.V., Colloid J., 2019, vol. 81, no. 3, pp. 272–276. https://doi.org/10.1134/S1061933X19030116

    Article  CAS  Google Scholar 

  5. Luss, A.L., Kulikov, P.P., Kuskov, A.N., and Shtil’man, M.I., Usp. Khim. Khim. Tekhnol., 2017, vol. 31, no. 11, pp. 64–66.

    Google Scholar 

  6. Terekhin, V.V., Dementjeva, O.V., and Rudoj, V.M., Russ. Chem. Rev., 2011, vol. 80, no. 5, pp. 453–470. https://doi.org/10.1070/RC2011v080n05ABEH004183

    Article  CAS  Google Scholar 

  7. Fong, W.M., Affam, A.C., and Chung, W.C., Int. J. Environ. Sci. Technol., 2020, vol. 17, pp. 3485–3494. https://doi.org/10.1007/s13762-020-02720-1

    Article  CAS  Google Scholar 

  8. Chernikova, E.V., Lysenko, E.A., Serkhacheva, N.S., and Prokopov, N.I., Polym. Sci., Ser. C, 2018, vol. 60, no. 2, pp. 192–218. https://doi.org/10.1134/S1811238218020042

    Article  CAS  Google Scholar 

  9. Derikov, Ya.I., Yablanovich, A.D., Litmanovich, E.A., Amarantov, S.V., Chernikova, E.V., and Kudryavtsev, Ya.V., Polym. Sci., Ser. B, 2021, vol. 63, no. 6, pp. 882–893. https://doi.org/10.1134/S1560090421060087

    Article  CAS  Google Scholar 

  10. Chernikova, E.V., Yulusov, V.V., Mineeva, K.O., Golubev, V.B., and Garina, E.S., Polym. Sci., Ser. B., 2011, vol. 53, nos. 7–8, pp. 437–447. https://doi.org/10.1134/S1560090411070025

    Article  CAS  Google Scholar 

  11. Chernikova, E.V., Poteryaeva, Z.A., Belyaev, S.S., Nifant’ev, I.E., Shlyakhtin, A.V., Kostina, Yu.V., Cherevan’, A.S., Efimov, M.N., Bondarenko, G.N., and Sivtsov, E.V., Polym. Sci., Ser. B., 2011, vol. 53, nos. 7–8, pp. 391–403. https://doi.org/10.1134/S1560090411070013

    Article  CAS  Google Scholar 

  12. Kreshkov, A.P., Bykova, L.N., and Kazaryan, N.A., Kislotno-osnovnoe titrovanie v nevodnykh rastvorakh (Acid–Base Titration in Nonaqueous Solutions), Moscow: Khimiya, 1967, p. 72.

    Google Scholar 

  13. Pratskova, S.E. and Khudaiberdina, D.R., Abstracts of Papers, Problemy teoreticheskoi i eksperimental’noi khimii: XXXI Rossiiskaya nauchnaya konferentsiya s mezhdunarodnym uchastiem, posvyashchennaya 90-letiyu so dnya rozhdenia professora V.M. Zhukovskogo (Problems of Theoretical and Experimental Chemistry: XXXI Russian Scientific Conf. with Int. Participation, Dedicated to the 90th Birthday Anniversary of Prof. V.M. Zhukovskii), Yekaterinburg, April 20–23, 2021, Yekaterinburg: Ural’skii Univ., 2021, p. 118.

  14. Kuskov, A.N., Kulikov, P.P., Babkina, S.S., and Shtil’man, M.I., Butlerovsk. Soobshch., 2014, vol. 38, no. 4, pp. 109–118.

    Google Scholar 

  15. Alexandridis, P. and Tsianou, M., Eur. Polym. J., 2011, vol. 47, pp. 569–583. https://doi.org/10.1016/j.eurpolymj.2010.10.021

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Chelyabinsk State University, 454001, Chelyabinsk, Russia

    O. I. Kropacheva, E. V. Nikolaichikova & S. E. Pratskova

  2. South Ural State (Research) University, 454080, Chelyabinsk, Russia

    D. A. Zherebtsov

Authors
  1. O. I. Kropacheva
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  2. E. V. Nikolaichikova
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  3. D. A. Zherebtsov
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  4. S. E. Pratskova
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Correspondence to O. I. Kropacheva.

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Translated from Zhurnal Prikladnoi Khimii, No. 10, pp. 1219–1237, October, 2022 https://doi.org/10.31857/S0044461822100036

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Kropacheva, O.I., Nikolaichikova, E.V., Zherebtsov, D.A. et al. Synthesis of Silver Particles in Micelles Stabilized by a Vinyl Acetate–N-Vinylpyrrolidone Block Copolymer. Russ J Appl Chem 95, 1533–1538 (2022). https://doi.org/10.1134/S1070427222100032

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