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Vanadium(IV) Polymer-Metal Complex Based on Salicylideneimine Derivative of N-Vinylpirrolidone Copolymier with N-Vinylamine

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Copolymers of N-vinylpyrrolidone with N-vinylsalicylideneimine, as well as water-soluble polymer-metal complexes of vanadium(IV) based on them, were synthesized. The obtained compounds were characterized by UV-Vis, IR, 1H NMR, atomic emission spectroscopy, the composition of the copolymer and the content of vanadium in the synthesized polymer-metal complex were determined. The probable structure of polymer-metal complex was proposed based on analysis of the data on composition of the copolymer and polymer-metal complex. Investigation of kinetics of VO2+ release under conditions close to physiological showed that the under these conditions the release of vanadyl ions may cause a potential hypoglycemic effect of the resulting polymer-metal complex.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    E. N. Dubrov, A. S. Kirillov, A. A. Selyutin, V. D. Krasikov & A. G. Ivanov

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  1. E. N. Dubrov
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  2. A. S. Kirillov
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  3. A. A. Selyutin
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  4. V. D. Krasikov
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  5. A. G. Ivanov
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Contributions

E.N. Dubrov: synthesis of copolymers and the preparation of a polymer-metal complex, determination of the molecular weights of the copolymer by viscometry; A.S. Kirillov: study of the polymer-metal complex by electron spectroscopy and kinetic studies; A.A. Selyutin: study of copolymers and polymer-metal complex by NMR spectroscopy; V.D. Krasikov: development and validation of analytical methods for the determination of vanadium in a polymer-metal complex; A.G. Ivanov: substantiation of the idea of carrying out research on the synthesis of vanadium polymer-metal complexes and their practical application, the study of the structure of copolymers and the polymer-metal complex by IR spectroscopy.

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Correspondence to E. N. Dubrov.

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Dubrov, E.N., Kirillov, A.S., Selyutin, A.A. et al. Vanadium(IV) Polymer-Metal Complex Based on Salicylideneimine Derivative of N-Vinylpirrolidone Copolymier with N-Vinylamine. Russ J Appl Chem 95, 1329–1335 (2022). https://doi.org/10.1134/S1070427222090075

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  • DOI: https://doi.org/10.1134/S1070427222090075

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