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Synthesis and Application of Non-Toxic Superhydrophobic Phenyl Substituted Pyrazolidine Based Benzoxazine Coating for Oil-Water Separation and Corrosion Resistance

  • Organic Synthesis and Industrial Organic Chemistry
  • Published:
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Abstract

The present work investigate the coating behaviors of a series of polybenzoxazines (PBZs) derived from N-phenyl pyrazolidine scaffold based bisphenol (PPBP) and long chain aliphatic amines. Initially, the prepared PPBP was verified for its non-toxicity in comparison with bisphenol-A. Subsequently, the PBZs prepared from PPBP displayed enhanced values of water contact angle (WCA) when coated over different substrates namely cotton fabric and mild steel. In specific, the poly(PPBP-dda) and poly(PPBP-oda) coated cotton fabrics delivered outstanding WCA values of 154.2° and 153.5°, respectively. Observations from SEM images suggest that poly(PPBP-dda), and poly(PPBP-oda) exhibit closely packed molecular arrangement contributing for rough surfaces due to presence of their long dodecyl(C12) and octadecyl(C18) chains, respectively. Subsequently the oil-water separation investigation using the poly(PPBP-dda) coated fabric delivered superior separation efficiency (98 %) and flux values [6330 L/(m2 h)]. At the same time, the mild steel specimens when coated with poly(PPBP-dda) was also found to be less aggressive towards corrosion in artificial sea-water showing 81% efficiency and charge transfer resistance (Rct) of 280 Ω cm–2. Further, screening of the PPBP monomer and corresponding polybenzoxazines exhibited good antibacterial activity. Thus, a new type of PPBP based PBZs prepared in present work can lead further development of various new non-toxic substrates to replace bis-phenol derivatives.

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ACKNOWLEDGMENTS

The authors acknowledge the SIF, VIT-Vellore for providing NMR facility.

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Authors and Affiliations

  1. Department of Chemistry, PSG Institute of Technology and Applied Research, Coimbatore, 641062, Tamil Nadu, India

    P. Nivinkrishnan, A. Kumaravel, P. Gokul, P. Prabunathan & M. Manoj

  2. Department of Chemistry, C. Kandaswami Naidu College for Women, Cuddalore, 607001, Tamil Nadu, India

    S. Jancy Sophia & R. Ramya

  3. Department of Chemistry, Sri Krishna College of Engineering and Technology, Coimbatore, 607001, Tamil Nadu, India

    M. Sangeetha

  4. Turiyam Research Laboratories, 605111, Puducherry, India

    P. Prabunathan & M. Manoj

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  1. P. Nivinkrishnan
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Correspondence to P. Prabunathan, M. Manoj or M. Sangeetha.

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Nivinkrishnan, P., Sophia, S.J., Kumaravel, A. et al. Synthesis and Application of Non-Toxic Superhydrophobic Phenyl Substituted Pyrazolidine Based Benzoxazine Coating for Oil-Water Separation and Corrosion Resistance. Russ J Appl Chem 95, 1243–1261 (2022). https://doi.org/10.1134/S1070427222080225

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