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Kinetics of Calcium Carbonate Dissolution in Carboxylic Acids

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Abstract

The study deals with treatment of carbonate reservoirs with carboxylic acid solutions. The kinetics of calcite dissolution in carboxylic acids was studied by volumetric analysis. The orders and rate constants of calcite dissolution at room temperature in solutions of hydroxy acids and aliphatic acids were studied. The dependence of the rate constants on the basicity and acidity parameter in the series of hydroxy acids and aliphatic acids was determined.

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ACKNOWLEDGMENTS

The authors are grateful to Engineer of Second Category A.V. Dektereva for determining the particle-size distribution of the powdered CaCO3 sample and to geologist E.P. Miklyaeva for performing X-ray diffraction analysis of CaCO3 samples.

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Authors and Affiliations

  1. Aprelevka Division, All-Russia Research Geological Petroleum Institute, Aprelevka, 143363, Moscow oblast, Russia

    N. A. Prokudina, A. S. Gabisov & V. A. Starkovskii

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  1. N. A. Prokudina
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  2. A. S. Gabisov
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  3. V. A. Starkovskii
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Correspondence to N. A. Prokudina.

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Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 781–786, July, 2022 https://doi.org/10.31857/S0044461822060111

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Prokudina, N.A., Gabisov, A.S. & Starkovskii, V.A. Kinetics of Calcium Carbonate Dissolution in Carboxylic Acids. Russ J Appl Chem 95, 866–871 (2022). https://doi.org/10.1134/S1070427222060118

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  • DOI: https://doi.org/10.1134/S1070427222060118

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