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Production of Carbon Dioxide Hydrates Using Frozen Aqueous Solutions of Polyvinyl Alcohol

  • Physicochemical Studies of Systems and Processes
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Abstract

The kinetics of the formation of carbon dioxide hydrates in frozen aqueous solutions of polyvinyl alcohol was studied. An excess of the factor of water conversion into carbon dioxide hydrate in frozen aqueous solutions of polyvinyl alcohol in comparison with dispersed ice was established. It is shown that the values of the rate and water-to-hydrate conversion factor under static conditions of hydrate formation (without stirring) in frozen aqueous solutions of polyvinyl alcohol can be higher compared to aqueous solutions of surfactants, powder cryogels of polyvinyl alcohol, microdroplet dispersed systems (“dry water”) under comparable conditions of hydrate formation.

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Funding

The study was supported by state order no. 121041600040-3.

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Authors and Affiliations

  1. Earth Cryosphere Institute, Tyumen Scientific Centre of Siberian Branch, Russian Academy of Sciences, 625026, Tyumen, Russia

    A. O. Drachuk, N. S. Molokitina, A. A. Kibkalo & L. S. Podenko

  2. Tyumen State University, 625003, Tyumen, Russia

    A. O. Drachuk & A. A. Kibkalo

  3. Kazan (Volga region) Federal University, 625003, Kazan, Russia

    N. S. Molokitina

Authors
  1. A. O. Drachuk
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  2. N. S. Molokitina
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  3. A. A. Kibkalo
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  4. L. S. Podenko
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Correspondence to A. O. Drachuk.

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Translated from Zhurnal Prikladnoi Khimii, No. 4, pp. 444–449, March, 2022 https://doi.org/10.31857/S0044461822040041

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Drachuk, A.O., Molokitina, N.S., Kibkalo, A.A. et al. Production of Carbon Dioxide Hydrates Using Frozen Aqueous Solutions of Polyvinyl Alcohol. Russ J Appl Chem 95, 506–511 (2022). https://doi.org/10.1134/S107042722204005X

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  • DOI: https://doi.org/10.1134/S107042722204005X

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