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Photocatalytic Activity of Fluorinated Titanium Dioxide in Ozone Decomposition

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Abstract

Nanocrystalline (~10 nm) fluorinated titanium dioxide was prepared by hydrothermal-microwave treatment. The powder obtained was applied onto the surface of porous quartz glass by impregnation; the TiO2 amount loaded was 0.87 wt %. As shown by in situ measurements, the material obtained exhibits high catalytic activity in ozone decomposition, exceeding that of commercial photocatalysts Hombikat UV100 and Evonik Aeroxide® TiO2 P25 by a factor of more than 1.5.

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Notes

  1. Resolution of the Chief State Sanitary Physician of the Russian Federation of January 28, 2021, no. 2: On Approval of Sanitary Rules and Regulations SanPiN 1.2.3685–21 “Hygienic Norms and Requirements to Ensuring the Safety and/or Harmlessness of Habitat Factors to Humans.”

  2. NAAQS, EPA, Criteria Pollutants, 2015. https://www.epa.gov/criteria-air-pollutants/naaqs-table.

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Funding

The study was performed within the framework of the government assignment for the Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of basic research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Sadovnikov, A. E. Baranchikov & V. K. Ivanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Sadovnikov, E. R. Naranov & A. L. Maksimov

Authors
  1. A. A. Sadovnikov
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  2. E. R. Naranov
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  3. A. L. Maksimov
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  4. A. E. Baranchikov
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  5. V. K. Ivanov
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Contributions

A.A. Sadovnikov: synthesis of the compound for the study and studies of the catalytic activity of the samples; E.R. Naranov: major fraction of work on physicochemical analysis of the samples and participation in preparation of figures; A.L. Maksimov: participation in setting the tasks of the study and analysis of the catalytic data; A.E. Baranchikov: major fraction of literature search and SEM examination of the samples; V.K. Ivanov: participation in setting the tasks of the study, evaluation of the performance of the photocatalysts.

Corresponding author

Correspondence to A. A. Sadovnikov.

Ethics declarations

A.L. Maksimov is the Editor-in-Chief of Zhurnal Prikladnoi Khimii/Russian Journal of Applied Chemistry. The other authors declare that they have no conflict of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 119–127, December, 2022 https://doi.org/10.31857/S0044461822010145

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Sadovnikov, A.A., Naranov, E.R., Maksimov, A.L. et al. Photocatalytic Activity of Fluorinated Titanium Dioxide in Ozone Decomposition. Russ J Appl Chem 95, 118–125 (2022). https://doi.org/10.1134/S1070427222010153

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