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Composite Fibers Based on Hydrated Cellulose and Poly-N-vinylpyrrolidone, Prepared from Cellulose Solutions in N-Methylmorpholine-N-Oxide

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Abstract

Hydrophilic composite fibers of various compositions were prepared from mixtures of solid solutions of cellulose in N-methylmorpholine-N-oxide or its monohydrate and poly-N-vinylpyrrolidone after bringing them to the viscous-flow state. The rheological behavior of cellulose–poly-N-vinylpyrrolidone systems in N-methylmorpholine-N-oxide with various water contents was studied. At the poly-N-vinylpyrrolidone content of up to 30 wt % relative to cellulose and a temperature of 100–120°С, the systems under consideration are emulsions whose rheological behavior is determined by specific features of the dispersed phase, character of the interface, and its stability under shear flow. The poly-N-vinylpyrrolidone dispersed phase, as well as its preliminary immobilization on cellulose, does not worsen the rheological properties of the melt, which allows preparation of composite fibers under the conditions similar to those of the formation of hydrated cellulose fibers. The results of studying the fibers by scanning electron microscopy, X-ray diffraction, and differential scanning calorimetry show that the fibers have dense microfibrillar structure without additional ordering caused by the phase interaction; they also demonstrate intense interphase interaction of the components. The mechanical characteristics of the fibers, determined by tensile tests, are comparable to those of hydrated cellulose fibers.

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ACKNOWLEDGMENTS

The authors are grateful to E.B. Krut’ko, staff member of the analytical laboratory of the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, for performing elemental analysis of the samples.

Funding

The study was performed within the framework of Russian Science Foundation grant no. 17-79-30108 and of the government assignment for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences using the equipment of the Center for Shared Use “Analytical Center for Problems of Deep Oil Refining and Petroleum Chemistry,” Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. A. Egorov, G. A. Shandryuk, M. I. Vinogradov, I. S. Levin, A. N. Tavtorkin & V. G. Kulichikhin

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  1. Yu. A. Egorov
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  2. G. A. Shandryuk
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  6. V. G. Kulichikhin
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Contributions

Yu.A. Egorov: collection of published data and preparation of literature review, planning of experiments, preparation of composite fibers, and study of their mechanical properties; G.A. Shandryuk: thermal study of fibers; M.I. Vinogradov: rheological measurements; I.S. Levin: X-ray diffraction analysis of fibers; A.N. Tavtorkin: examination of fibers by scanning electron microscopy; V.G. Kulichikhin: development of methodology for preparing composite fibers and studying their properties.

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Correspondence to Yu. A. Egorov.

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Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 100–113, December, 2022 https://doi.org/10.31857/S0044461822010121

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Egorov, Y.A., Shandryuk, G.A., Vinogradov, M.I. et al. Composite Fibers Based on Hydrated Cellulose and Poly-N-vinylpyrrolidone, Prepared from Cellulose Solutions in N-Methylmorpholine-N-Oxide. Russ J Appl Chem 95, 100–112 (2022). https://doi.org/10.1134/S107042722201013X

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