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Successive Modification of Montmorillonite with Quaternary Alkylammonium Salts of Various Structures as a Method of Preparing Nanofillers for in situ Synthesis of Polymer Nanocomposites

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An Erratum to this article was published on 01 February 2022

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Abstract

In accordance with the suggested procedure, the strength characteristics of polymers prepared by radical polymerization of vinyl polymers are enhanced by grafting the monomers to the nanofiller surface. When preparing high-strength polymer–aluminosilicate nanocomposites by radical polymerization in situ, it is appropriate to ensure both grafting of polymer chains to the aluminosilicate surface of the filler (montmorillonite) and hydrophobization of the nanofiller surface. To solve this problem, successive modification of montmorillonite with two quaternary ammonium salts with different properties was studied. Fillers with mixed modifiers were prepared, and their structure was determined. Studies of composites with such fillers confirmed the appropriateness of using the mixture of modifiers for preparing the filler: The nanocomposite based on butyl methacrylate, containing organoclay with the mixed modifier, surpasses in the Young’s modulus both unfilled poly(butyl methacrylate) and composites containing nanoclays with the individual modifiers.

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ACKNOWLEDGMENTS

The study was performed using the equipment of the Center for Shared Use “Analytical Center for Problems of Deep Oil Refinement and Petroleum Chemistry,” Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

Funding

The study was performed within the framework of the government assignment for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    V. A. Gerasin, I. M. Pogodin, V. V. Kurenkov & D. I. Mendeleev

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    V. A. Gerasin & I. M. Pogodin

Authors
  1. V. A. Gerasin
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  2. I. M. Pogodin
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  3. V. V. Kurenkov
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  4. D. I. Mendeleev
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Corresponding authors

Correspondence to V. A. Gerasin or V. V. Kurenkov.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 56–66, December, 2022 https://doi.org/10.31857/S0044461822010078

The original online version of this article was revised: There are four authors in the article. The author I.M. Pogodin is omitted by a mistake. The authors should read as V. A. Gerasin, I. M. Pogodin, V. V. Kurenkov, and D. I. Mendeleev.

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Gerasin, V.A., Pogodin, I.M., Kurenkov, V.V. et al. Successive Modification of Montmorillonite with Quaternary Alkylammonium Salts of Various Structures as a Method of Preparing Nanofillers for in situ Synthesis of Polymer Nanocomposites. Russ J Appl Chem 95, 59–69 (2022). https://doi.org/10.1134/S1070427222010086

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