Abstract
In this work, CuO thin films were deposited by successive ionic layer adsorption and reaction (SILAR) method at room temperature. The synthesis parameters of the method were changed to examine the details of the production method. Our main goal was the optimization of the deposited CuO thin films in terms of their structural, optical and electrical properties depending on the pH (11, 11.2, and 11.4) and temperature (70, 80, and 90°C) of hot water in the production cycle. XRD analysis showed that crystallite size increases with the increase in temperature of hot water in the production cycle. The crystallite size has also changed according to pH, but no linear increase or decrease was observed. SEM analysis showed that the change of structural parameters has considerably affected the morphology of the produced films. Optical bandgaps of the synthesized CuO thin films decreased with the increase in pH value and/or temperature of hot water in the production cycle and this behavior could be best attributed to the grain size enhancement. Moreover, all films showed a decrease in resistance with the increase in temperature of the hot water in the production cycle. On the other hand, the lowest resistances were achieved for CuO thin films produced at a pH of 11.2, beyond which resistances increased with the further increase in pH value.
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15 February 2022
An Erratum to this paper has been published: https://doi.org/10.1134/S1070427221100074
REFERENCES
Morales, J., Sanchez, L., Martin, F., Romos-Barrado, J.R., and Sanchez, M., Electrochim. Acta , 2004, vol. 49, no. 26, pp. 4589–4597 https://doi.org/10.1016/j.electacta.2004.05.012
Zheng, L. and Liu, X., Mater. Lett., 2007, vol. 61, no. 11–12, pp. 2222–2226. https://doi.org/10.1016/j.matlet.2006.08.063
Gençyılmaz, O. and Taşkoprü, T., J. Alloys Compd., 2017, vol. 695, pp. 1205–1212, https://doi.org/10.1016/j.jallcom.2016.10.247
Akaltun, Y., Thin Solid Films, 2015, vol. 594, part A, pp. 30–34 https://doi.org/10.1016/j.tsf.2015.10.003
Lillo-Ramiro, J., Guerrero-Villalba, J.M., de L. Mota-Gonzalez, M., Aguirre- Tostado, F.S., Gutierrez-Heredia, G., Mejía-Silva, I., and Carrillo-Castillo, A., Optik, 2021, vol. 229, no. 166238, pp. 1–13 https://doi.org/10.1016/j.ijleo.2020.166238
Yang, B., Liu, J., Qin, H., Liu, Q., Jing, X., Zhang, H., Li, R., Huang, G., and Wang, J., Ceram. Intern. 2018, vol. 44, no. 9, pp. 10426–10432 https://doi.org/10.1016/j.ceramint.2018.03.059
Sun, Q., Shi, X., Wang, X., Zhai, Y., Gao, L., Li, Z., Hao, Y., and Wu, Y., Org. Electron., 2019, vol. 75, ID 105428, pp. 1–7. https://doi.org/10.1016/j.orgel.2019.105428
Yang, Y., Yang, J., Yin, W., Huang, F., Cui, A., Zhang, D., Li, W., Hu, Z., and Chu, J., Appl. Surf. Sci., 2019, vol. 481, pp. 632–636. https://doi.org/10.1016/j.apsusc.2019.03.130
Shinde, S.K., Yadav, H.M., Ghodake, G.S., Kadam, A.A., Kumbhar, V.S., Yang, J., Hwang, K., Jagadale, A.D., Kumar, S., and Kim, D.Y., Colloids Surf B Biointerfaces, 2019, vol. 181, pp. 1004–1011. https://doi.org/10.1016/j.colsurfb.2019.05.079
Chen, Y, Yan, D., Jin, X., Zeng, Y., Zhang, D., Liu, Z., He, W., Wang, S., Wang, Z., Liu, Y., Zhang, W., and Huang, Y., Appl. Surf. Sci., 2019, vol. 491, pp. 206–215. https://doi.org/10.1016/j.apsusc.2019.06.117
Mersian, H. and Alizadeh, M., Ceram. Intern., 2020, vol. 46, pp. 17197–17208. https://doi.org/10.1016/j.ceramint.2020.03.275
Shinde, S.K., Ghodake, G.S., Fulari, V.J., and Kim, D.-Y., J Ind Eng Chem 2017, vol. 52, pp. 12–17. https://doi.org/10.1016/j.jiec.2017.03.049
Zgair, I.A., Omran Alkhayatt, A.H., Muhmood, A.A., and Hussain, S. K., Optik , 2019, vol. 191, pp. 48–54 . https://doi.org/10.1016/j.ijleo.2019.06.008
Karaduman Er, I., Yıldırım, M.A., Örkçü, H.H., Ateş, A., and Acar, S.,Appl. Phys. A, 2021, vol. 127, ID 230, pp. 1–14. https://doi.org/10.1007/s00339-021-04354-7
Sales Amalraj, A. and Senguttuvan, G., J Mater Sci: Mater Electron , 2014, vol. 25, pp. 2035–2040. https://doi.org/10.1007/s10854-014-1825-2
Bayansal, F., Sahin, B., Yuksel, M., and Cetinkara, H.A., Mater. Lett., 2013, vol. 98, pp. 197–200. https://doi.org/10.1016/j.matlet.2013.02.030
Bayansal, F., Sahin , B., Yüksel, M., Biyikli, N., Çetinkara, H.A., and Güder, H.S., J. Alloys Compd., 2013, vol. 566, pp. 78–82. https://doi.org/10.1016/j.jallcom.2013.03.018
Ghos, B.C., Uddin Farhad, S.F., Majed Patwary Md, A., Majumder, S., Hossain, Md.A., Islam Tanvir, N., Rahman, M.A., Tanaka, T., and Guo, Q., ACS Omega , 2021, vol. 6, pp. 2665–2674. https://doi.org/10.1021/acsomega.0c04837
Sahin, B. and Kaya, T., Appl. Surf. Sci., 2016, vol. 362, pp. 532–537. https://doi.org/10.1016/j.apsusc.2015.11.136
Çayır Taşdemirci, T., Elect. Mater. Lett., 2020, vol. 16, pp. 239–246. https://doi.org/10.1007/s13391-020-00205-4
Aydin, R and Cavusoglu, H, Mater. Res. Express, 2019, vol. 6, no. 086403, pp. 1–31. https://doi.org/10.1088/2053-1591/ab1a08
Yuksel, M., Pennings, J.R., Bayansal, F., and Yeow, J.T.W., Phys. Rev. B Condens. Matter 2020, vol. 599, no. 412578, pp. 1–5. https://doi.org/10.1016/j.physb.2020.412578
Mageshwari, K. and Sathyamoorthy, R., Mater. Sci. Semicond. Process., 2013, vol. 16, pp. 337–343. https://doi.org/10.1016/j.mssp.2012.09.016
Daoudi, O., Qachaou, Y., Raidou, A., Nouneh, K., Lharch, M., and Fahoume, M., Superlattices Microstruct. 2019, vol. 127, pp. 93–99. https://doi.org/10.1016/j.spmi.2018.03.006
.Ravi Dhas, C., Alexander, D., Jennifer Christy, A., Jeyadheepan, K., Moses Ezhil Raj, A., and Sanjeevi Raja, C., Asian J. Appl. Sci., 2014, vol. 7, no. 8, pp. 671-684. https://doi.org/10.3923/ajaps.2014.671.684
Cavusoglu, H., J. Mater. Sci.: Mater. Electron, 2018, vol. 29, pp. 12777–12784. https://doi.org/10.1007/s10854-018-9396-2
Bade, B.R., Rondiya, S.R., Hase, Y.V., Nasane, M.P., Jathar, S.B., Barma, S.V., Kore, K.B., Nilegave, D.S., Jadkar, S.R., and Funde, A.M., AIP Conference Proceedings, 2021, vol. 2335, no. 100001, pp. 1–6. https://doi.org/10.1063/5.0043341
Sathya, M. and Pushpanathan, K., Appl. Surf. Sci., 2018, vol. 449, pp. 346–357 https://doi.org/10.1016/j.apsusc.2017.11.127
Mariappan, R., Ponnuswamy, V., Chandra Bose, A., Chithambararaj, A., Suresh, R., and Ragavendar, M., Superlattices Microstruct. 2014, vol. 65, pp. 184–94. https://doi.org/10.1016/j.spmi.2013.10.005
Srinivasan, G., Rajendra Kumar, R.T., and Kumar, J., J. Sol-Gel. Sci. Technol., 2007, vol. 43, pp. 171–177. https://doi.org/10.1007/s10971-007-1574-2
Visalakshi, S., Kannan, R., Valanarasu, S., Kathalingam, A., and Rajashabala, S., Materials Research Innovations, 2016, vol. 21, no. 3, pp. 146–151.
Saadat Niavol, S. and Ghodsi, F.E., Russ. J. Phys. Chem., 2013, vol. 87, no. 1, pp. 84–87. https://doi.org/10.1134/S0036024413010214
Maiti, U.N., Ghosh, P.K., Amed, Sk,F., Mitra, M.K., and Chattopadhyay, K.K., J. Sol-Gel Sci Techn.,v2007, vol. 41, pp. 87–92. https://doi.org/10.1007/s10971-006-0116-7
Cortes, A., Gómez, H., Marotti, R.E., Riverosa, G., and Dalchiele, E.A., Solar Energy Materials and Solar Cells, 2004, vol. 82, no. 1–2, pp. 21–34. https://doi.org/10.1016/j.solmat.2004.01.002
Luo, L.-B., Wang, X.-H., Xie, C., Li, Z.-J., Lu, R., Yang, X.-B., and Lu, J., Nanoscale Res. Lett. 2014, vol. 9, no. 637, pp. 1–8. http://www.nanoscalereslett.com/content/9/1/637.
Uddin, J., Sharmin, M., Hasan, M.N., and Podder, J., Optical Materials, 2021, vol. 119, no. 111388, pp. 1–9. https://doi.org/10.1016/j.optmat.2021.111388
Zare Asl, H. and Mohammad Rozati, S., Materials Research, 2018, vol. 21, no. 2, e20170754, pp. 1–8. https://doi.org/10.1590/1980-5373-MR-2017-0754
Gençyılmaz, O. and Taşköprü ,T., Dokuz Eylul University-Faculty of Engineering Journal of Science and Engineering, 2017, vol. 19, no. 56, pp. 468–483. https://doi.org/10.21205/deufmd.2017195646
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Er, I.K. Effect of Synthesis Parameters on the Structural, Optical and Electrical Properties of Successive Ionic Layer Adsorption and Reaction (SILAR)-Deposited CuO Thin Films. Russ J Appl Chem 94, 1334–1343 (2021). https://doi.org/10.1134/S1070427221090160
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DOI: https://doi.org/10.1134/S1070427221090160