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Heat Release Kinetics in Thermally Initiated 1,4-Diethynylbenzene Polymerization

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

The heat release kinetics in thermally initiated polymerization of 1,4-diethynylbenzene suggested as fuel dispersant in gas generator engines was studied under isothermal conditions in the temperature interval 90–150°С in the melt–vapor two-phase closed system. The enthalpies and entropies of melting, vaporization, and sublimation of 1,4-diethynylbenzene and the kinetics of a decrease in its vapor pressure in the course of polymerization in the melt were determined. Specific features of pressure and temperature variation in the course of propagation of the 1,4-diethynylbenzene combustion front in a cylindrical specimen in a Crawford bomb at the initial pressure of 2 MPa were studied.

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Funding

The study was financially supported by the Institute of Problems of Chemical Physics, Russian Academy of Sciences, themes 0089-2019-0005 (state registry no. АААА-А19-119101690058-9), Basic and Problem-Oriented Research in the Field of the Development of Energetic Condensed Systems (ECSs) for Various Purposes, and 0089-2019-0017 (state registry no. АААА-А19-119100800130-0), Complex Basic and Problem-Oriented Research in the Field of Physics and Chemistry of Combustion and Heat and Mass Exchange of High-Energy-Capacity Solid and Liquid Fuels and Materials of New Generation for High-Temperature Ramjet Combustion Chambers.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    A. I. Kazakov, D. B. Lempert, A. V. Nabatova, T. S. Larikova, A. A. Molokanov, I. N. Zyuzin, N. N. Volkova, M. B. Kislov, A. F. Zholudev & L. S. Yanovskii

  2. Moscow State University, 119991, Moscow, Russia

    L. S. Yanovskii

Authors
  1. A. I. Kazakov
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  2. D. B. Lempert
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  3. A. V. Nabatova
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  4. T. S. Larikova
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  5. A. A. Molokanov
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  6. I. N. Zyuzin
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  7. N. N. Volkova
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  8. M. B. Kislov
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  9. A. F. Zholudev
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  10. L. S. Yanovskii
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Contributions

A.I. Kazakov: analysis of published data on thermally initiated 1,4-diethynylbenzene polymerization, processing of experimental data on the heat release and on a decrease in the vapor pressure in 1,4-diethynylbenzene polymerization, and writing of Introduction and sections concerning the procedure for studying the heat release rates, the kinetic of the heat release in thermally initiated 1,4-diethynylbenzene polymerization, the temperature dependence of the 1,4-diethynylbenzene vapor pressure, and the kinetics of its decrease in the course of 1,4-diethynylbenzene polymerization in the melt; D.B. Lempert: suggestion of using 1,4-diethynylbenzene as a dispersant and participation in setting the tasks and formulating the conclusions of the study; A.V. Nabatova: experiments on the determination of the heat release rates in 1,4-diethynylbenzene polymerization and computer processing of the data obtained; T.S. Larikova: experiments on determining the 1,4-diethynylbenzene vapor pressure and the kinetics of its decrease in the course of polymerization; A.A. Molokanov: processing of experimental data on the temperature dependence of the 1,4-diethynylbenzene vapor pressure and calculation of changes in the thermochemical parameters upon phase transitions; I.N. Zyuzin: preparation of 1,4-diethynylbenzene samples for the studies and writing of the Experimental section; N.N. Volkova: processing of the experimental data on the high-temperature conversion of 1,4-diethynylbenzene, collection of the literature, writing of the sections concerning relationships of the pressure and temperature variation in 1,4-diethynylbenzene combustion and, in part, procedure for studying the heat release rates; M.B. Kislov and A.F. Zholudev: experiment on studying the macrokinetic relationships of the 1,4-diethynylbenzene combustion in the constant-pressure bomb; L.S. Yanovskii: participation in setting the tasks of the study.

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Correspondence to A. I. Kazakov.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 7, pp. 927–936, January, 2021 https://doi.org/10.31857/S004446182107015X

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Kazakov, A.I., Lempert, D.B., Nabatova, A.V. et al. Heat Release Kinetics in Thermally Initiated 1,4-Diethynylbenzene Polymerization. Russ J Appl Chem 94, 977–985 (2021). https://doi.org/10.1134/S1070427221070168

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