Abstract
Lithium–lead alloys are of main interest in the liquid state. They were subjects of numerous studies, in particular, of those dealing with structural ordering in the liquid phase. Lithium–lead alloys show promise for use in liquid metal energy conversion systems and in nuclear power engineering. The results of studying thermodynamic properties of liquid Li–Pb alloys by various methods in the period from 1973 to 2018 are summarized and analyzed in the paper. Treatment of the whole set of the experimental data allowed choice of the recommended values of the thermodynamic functions for the composition interval that is of interest for technological purposes (0 ≤ xLi ≤ 0.50, with a step of 0.05). The calculation results are presented in the tabular form and are described by polynomials.
Similar content being viewed by others
REFERENCES
Kim, H., Boysen, D.A., Newhouse, J.M., Spatocco, B.L., Chung, B., Burke, P.J., Bradwell, D.J., Jiang, K., Tomaszowska, A.A., Wang, K., Wei, W., Ortiz, L.A., Barrida, S.A., Poizeau, S.M., and Sadoway, D.R., Chem. Rev., 2013, vol. 138, pp. 2075–2093. https://doi.org/10.1021/cr300205k
Wang, K., Jiang, K., Chung, B., Ouchi, T., Burke, P.J., Boysen, D.A., Bradwell, D.J., Kim, H., Muecke, U., and Sadoway, D. R., Nature, 2014, vol. 514, no. 7522, pp. 348–350. https://doi.org/10.1038/nature13700
Okamoto, H., J. Phase Equil., 1993, vol. 14, no. 6, p. 770
Hubberstey, P., Sample, T., and Barker, M.G., J. Nucl. Mater., 1992, vols. 191–194, pp. 283–287.
Zhou, C., Guo, C., Li, C., and Du, Z., J. Nucl. Mater., 2016, vol. 477, pp. 95–101. https://doi.org/10.1016/j.jnucmat.2016.04.061
Ruppersberg, H. and Egger, H., J. Chem. Phys., 1975, vol. 63, pp. 4095–4103.
Ruppersberg, H. and Schirmacher, W., J. Phys. F: Met. Phys., 1984, vol. 14, pp. 2787–2795.
Demidov, A.I., Morachevskii, A.G., and Gerasimenko, L.N., Elektrokhimiya, 1973, vol. 9, pp. 848–851.
Terliсka, S., Debski, A., and Gasior, W., J. Mol. Liq., 2018, vol. 249, pp. 66–72. https://doi.org/10.1016/j.molliq.2017.11.013
Komarek, K.L., Pure Appl. Chem., 1992, vol. 64, no. 1, pp. 93–102.
Morachevskii, A.G., Voronin, G.F., Geiderikh, V.A., and Kutsenok, I.B., Elektrokhimicheskie metody issledovaniya v termodinamike metallicheskikh sistem (Electrochemical Methods of Investigation in Thermodynamics of Metal Systems), Moscow: Akademkniga, 2003.
Morachevskii, A.G. and Firsova, E.G., Termodinamika zhidkikh metallov i splavov (Thermodynamics of Liquid Metals and Alloys), St. Petersburg: Lan’, 2016.
Sommer, F., J. Therm. Anal., 1988, vol. 33, no. 1, pp. 15–28.
Morachevskii, A.G. and Demidov, A.I., Zh. Fiz. Khim., 1983, vol. 57, no. 9, pp. 2113–2128.
Yatsenko, S.P. and Saltykova, E.A., Zh. Fiz. Khim., 1976, vol. 50, no. 8, pp. 2129–2130.
Saboungi, M.-L., Marr, J., and Blander, M., J. Chem. Phys., 1978, vol. 68, no. 4, pp. 1375–1384.
Predel, B. and Oehme, G., Z. Metallkunde, 1979, vol. 70, no. 7, pp. 450–453.
Neubert, A., J. Chem. Thermodyn., 1979, vol. 11, no. 10, pp. 971–977.
Becker, W., Schwitzgebel, G., and Ruppersberg, H., Z. Metallkunde, 1981, vol. 7, no. 3, pp. 186–190.
Gasior, W. and Moser, Z., J. Nucl. Mater., 2001, vol. 294, pp. 77–83. https://doi.org/10.1016/S0022-3115(01)00440-8
Morachevskii, A.G., Russ. J. Appl. Chem., 2014, vol. 87, no. 12, pp. 1783–1803. https://doi.org/10.1134/S1070427214120015
Belashchenko, D.K., Struktura zhidkikh i amorfnykh metallov (Structure of Liquid and Amorphous Metals), Moscow: Metallurgiya, 1985.
Morachevskii, A.G. and Kozin, L.F., Thermodynamics of associated melts, Termodinamika i materialovedenie poluprovodnikov (Thermodynamics and Materials Science of Semiconductors), Glazov, V.M., Ed., Moscow: Metallurgiya, 1992, pp. 53–74.
Saboungi, M.-L., Geerstma, W., and Price, D.L., Ann. Rev. Phys. Chem., 1990, vol. 41, pp. 207–244.
Mas de les Vall, E., J. Nucl. Mater., 2008, vol. 376, pp. 353–357. https://doi.org/10.1016/J.JNUCMAT.2008.02.016
Fraile, A., Cuesta-Lopez, S., and Perlado, J.M., Trans. Fusion Sci. Technol., 2012, vol. 61, January, pp. 77–82. https://doi.org/10.13182/FST12-A13400
Gan, X., Xiao, S., Deng, H., Wang, B., Sun, X., Li, X., and Hu, W., Fusion Eng. Des., 2014, vol. 89, pp. 2946–2952. https://doi.org/10.1016/j.fusengdes.2014.09.016
Martelli, D., Venturini, A., and Utili, M., Fusion Eng. Des., 2019, vol. 138, pp. 183–195. https://doi.org/10.1016/j.fusengdes.2018.11.028
Temnogorova, N.V., Demidov, A.I., and Morachevskii, A.G., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1979, no. 3, pp. 89–96.
Avaliani, A.Sh., Kipiani, G.N., Mindin, V.Yu., and Shulaya, L.N., Zh. Prikl. Khim., 1988, vol. 61, no. 2, pp. 401–402.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
A.G. Morachevskii is a member of the Editorial Board of Zhurnal Prikladnoi Khimii/Russian Journal of Applied Chemistry. E.G. Firsova declares that she has no conflict of interest.
Additional information
Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 683–689, January, 2021 https://doi.org/10.31857/S0044461821060013
Rights and permissions
About this article
Cite this article
Morachevskii, A.G., Firsova, E.G. Thermodynamic Description of Liquid Lithium–Lead Alloys. Russ J Appl Chem 94, 699–705 (2021). https://doi.org/10.1134/S107042722106001X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S107042722106001X