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Evolution of the Structure of Aluminosilicate Particles in the Course of Formation of Nanocomposite Coatings Based on Alkyd Oligomers

  • Composite Materials
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Abstract

Various steps of the formation of nanocomposite coatings using organic-soluble film-forming agents are accompanied by changes in the structure of the aluminosilicate nanofiller under the action of various factors. Taking these factors into account is necessary for the development of coatings of preset structure with optimum properties. Swelling of various organoclays in pure and technical solvents and in a solution of an alkyd oligomeric film-forming agent was studied. The stability of organoclay dispersions in these media, the nanostructure of organoclay tactoids in dispersions, and the nanostructure of films of cured composites based on the alkyd oligomer were correlated. Factors favoring the swelling of organoclays in a film-forming agent solution and the formation of an intercalated nanocomposite were revealed. The effect of water vapor on the nanofiller structure in the composite film was characterized to evaluate the moisture resistance of the composite.

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Funding

This work was carried out within the State Program of TIPS RAS (Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences).

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    V. V. Kurenkov, A. A. Piryazev & V. A. Gerasin

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    A. A. Piryazev

Authors
  1. V. V. Kurenkov
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  2. A. A. Piryazev
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  3. V. A. Gerasin
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Correspondence to V. V. Kurenkov.

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Translated from Zhurnal Prikladnoi Khimii, No. 4, pp. 496–506, January, 2021 https://doi.org/10.31857/S0044461821040095

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Kurenkov, V.V., Piryazev, A.A. & Gerasin, V.A. Evolution of the Structure of Aluminosilicate Particles in the Course of Formation of Nanocomposite Coatings Based on Alkyd Oligomers. Russ J Appl Chem 94, 491–500 (2021). https://doi.org/10.1134/S1070427221040091

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