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Thermodynamic Simulation for Interaction of Polychlorinated Biphenyls with Potassium Hydroxide in Polyalkanolamines

  • Organic Synthesis and Industrial Organic Chemistry
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An Erratum to this article was published on 01 April 2021

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Abstract

The interaction of congeners of technical mixtures of polychlorbiphenyls (brands Trichlorobiphenyl, Sovol) with potassium hydroxide in polyalkanolamine medium [diethanolamine, triethanolamine, 2-(N,N-dimethylamino)ethanol, 3-(N,N-dimethylamino)-1-propylene, N-methyldiethanolamine] was studied. It was found that diethanolamine and triethanolamine are the most effective solvents affording the maximum conversion of the initial congeners of mixtures of polychlorinated biphenyls at a temperature of 200°C under conditions of nucleophilic substitution.

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Funding

This work was supported by the Russian Foundation for Basic Research (Grant no. 18-29-24126).

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Authors and Affiliations

  1. Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    A. V. Maiorova, T. I. Gorbunova & M. G. Pervova

  2. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    M. G. Pervova

Authors
  1. A. V. Maiorova
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  2. T. I. Gorbunova
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  3. M. G. Pervova
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Correspondence to A. V. Maiorova.

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The authors declare that they have no conflicts of interest requiring disclosure in this article.

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Translated from Zhurnal Prikladnoi Khimii, No. 3, pp. 346–352, January, 2021 https://doi.org/10.31857/S0044461821030099

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Maiorova, A.V., Gorbunova, T.I. & Pervova, M.G. Thermodynamic Simulation for Interaction of Polychlorinated Biphenyls with Potassium Hydroxide in Polyalkanolamines. Russ J Appl Chem 94, 330–336 (2021). https://doi.org/10.1134/S1070427221030095

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  • DOI: https://doi.org/10.1134/S1070427221030095

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