Abstract
A series of hierarchical CoAPO-5 molecular sieves was hydrothermally synthesized using cetyltrimethylammonium bromide (CTAB) as the template. The structural properties of CoAPO-5 molecular sieves with different amount of CTAB, including AFI-0.10, AFI-0.25, AFI-0.35, AFI-0.45 and AFI-0.55 were all characterized by XRD, SEM, N2 adsorption-desorption and NH3-TPD. The catalytic performance of as-prepared CoAPO-5 molecular sieves for the oxidation of furfural to maleic acid was investigated. Research results indicated that the structure characteristics as well as the catalytic performances of CoAPO-5 molecular sieves were strongly affected by CTAB amount. Among those hierarchical CoAPO-5 catalysts, AFI-0.45 sample exhibited highest maleic acid yield of 85.9% at 60℃ after 3 h reaction. In addition, the stability of AFI-0.45 was proved persistent for subsequent cycles.
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ACKNOWLEDGMENTS
This work is supported by the National Natural Science Foundation of China (21706017) and Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology (BM2012110), a Project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
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Zheng, L., Sun, X., Wang, J. et al. Effect of CTAB on the Oxidation of Furfural to Maleic Acid over Hierarchical CoAPO-5 Catalysts. Russ J Appl Chem 94, 237–244 (2021). https://doi.org/10.1134/S1070427221020142
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DOI: https://doi.org/10.1134/S1070427221020142