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Hydrogen Storage Using Liquid Organic Carriers

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Abstract

Published data on experimental and theoretical studies of systems for long-term storage and transportation of hydrogen, based on liquid organic hydrogen carriers operating in hydrogenation–dehydrogenation cycles, are reviewed. Comparative analysis of the hydrogen capacity and hydrogenation–dehydrogenation conditions was made for various classes of organic compounds used as hydrogen carriers (cycloalkanes, polycyclic alkanes, hydrocarbons containing heteroatoms, etc.). The catalysts (heterogeneous catalysts based on noble metals) and designs of reactors (including those with proton-exchange membranes) used for efficient and selective dehydrogenation of organic hydrogen carriers were also compared.

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Notes

  1. https://www.persistencemarketresearch.com/market-research/hydrogen-market.asp

  2. http://ieahydrogen.org/Activities/Task-32.aspx

  3. ISO 14687:2019 Hydrogen fuel quality—Product specification. https://www.iso.org/ru/standard/69539.html

  4. https://www.shokubai.org/tocat8/pdf/Plenary/PL9.pdf

  5. https://www.energy.gov/eere/fuelcells/downloads/technical-assessment-organic-liquid-carrier-hydrogen-storage-systems

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Funding

The study was performed within the Basic Research Program of State Academies of Sciences, theme 0089-2019-0018 for the Institute of Problems of Chemical Physics, Russian Academy of Sciences (state registry no. АААА-А19-119022690098-3).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    I. A. Makaryan & I. V. Sedov

  2. Moscow State University, 119991, Moscow, Russia

    I. V. Sedov & A. L. Maksimov

  3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maksimov

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A.L. Maksimov is the Editor-in-Chief of Zhurnal Prikladnoi Khimii/Russian Journal of Applied Chemistry. The other authors declare that they have no conflict of interest.

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Translated from Zhurnal Prikladnoi Khimii, No. 12, pp. 1716-1733, December, 2020 https://doi.org/10.31857/S0044461820120038

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Makaryan, I.A., Sedov, I.V. & Maksimov, A.L. Hydrogen Storage Using Liquid Organic Carriers. Russ J Appl Chem 93, 1815–1830 (2020). https://doi.org/10.1134/S1070427220120034

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  • DOI: https://doi.org/10.1134/S1070427220120034

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