Abstract
The results of studying the dependence of the reaction rate of the hydrogen sulfide oxidation in oil with molecular oxygen in the presence of an ammonia solution of cobalt phthalocyanine on the process temperature, the consumption of the catalyst complex, and the concentration of cobalt phthalocyanine in the catalyst complex are reported. It was shown that the rate of the hydrogen sulfide oxidation strongly depends on the consumption of the catalyst complex and the concentration of cobalt phthalocyanine in the catalyst complex. Based on experimental data, a mathematical model was derived that describes the hydrogen sulfide oxidation with satisfactory accuracy. The calculated values obtained using this mathematical model are in good agreement with the experimental data.
Similar content being viewed by others
REFERENCES
Ismagilov, F.R., Bogatyrev, T.S., Kurochkin, A.V., Denil'khanov, M.N., and Kozlova, I.I., Tekhnologii Nefti Gaza, 2013, no. 6, pp. 3–9.
Sakhabutdinov, R.Z., Shatalov, A.N., Garifullin, R.M., Shipilov, D.D., and Mukhametgaleev, R.R., Podgotovka i ochistka nefti ot serovodoroda (Preparation and Purification of Oil from Hydrogen Sulfide), Kazan: Ikhlas, 2012.
Podlesnova, E.V., Leont'eva, S.A., Botin, A.A., Alatortsev, E.I., Dmitrieva, A.A., and Bokov, S.A., Neftepererab. Neftekhimiya, 2019, no. 10, pp. 26–29.
Kelland, M.A., Production Chemicals for the Oil and Gas Industry, New York: CRC Press, 2014.
Bakke, J.M. and Buhaug, J.B., Ind. Eng. Chem. Res., 2004, vol. 43, pp. 1962–1965. https://doi.org/10.1021/ie030510c
Khuramshin, R.T., Ismagilov, F.R., Vishnevskaya, E.E., Isichenko, I.V., and Rakhmanov, E.V., Mir Nefteproduktov, Vestn. Neft. Kompanii, 2018, no. 3, pp. 4–10.
Vartapetyan, A.R., Zuikov, A.A., Monakhov, A.N., and Fedorov, I.I., Nauch.-Tekhn. Vestn. OAO NK Rosneft, 2016, no. 4, pp. 82–86.
Tyshchenko, V.A., Fedorov, I.I., Chernova, M.M., Chernova, V.M., Berkovich, K.V., Ovchinnikov, K.A., Dolganov, R.A., Spiridonova, I.V., and Zanozina, I.I., Tekhnologii Nefti Gaza, 2017, no. 2, pp. 14–17.
Madsen, H.T. and Sogaard, E.G., Petrol. Sci. Technol., 2014, vol. 32, pp. 2230–2238. https://doi.org/10.1080/10916466.2013.783066
Dzheksenov, M.K., Ismagilova, Z.F., and Ismagilov, F.R., Neftepererab. Neftekhimiya, 2018, no. 11, pp. 6–11.
Mazgarov, A.M. and Vil’danov, A.F., Petrol. Chem., 1999, vol. 39, no. 5, pp. 336–343.
RF Patent 2272065 (Publ. 2006).
Vil’danov, A.F., Aslyamov, I.R., Khrushcheva, I.K., Ayupova, N.R., Mazgarov, A.M., and Safiullina, A.K., Neft. Khoz-vo, 2012, no. 11, pp. 138–140.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest requiring disclosure in this article.
Rights and permissions
About this article
Cite this article
Kornetova, O.M., Mazgarov, A.M., Vil’danov, A.F. et al. Liquid-Phase Oxidation of Hydrogen Sulfide in Oil with Molecular Oxygen in the Presence of an Ammonia Solution of Cobalt Phthalocyanine. Russ J Appl Chem 93, 1421–1426 (2020). https://doi.org/10.1134/S1070427220090153
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427220090153