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Properties of Solutions of Cellulose and Chitin with Montmorillonite Nanoparticles in Aqueous Alkali with Urea and Thiourea Additions and of Composite Films Prepared from These Solutions

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Abstract

Rheological properties of cellulose and chitin solutions with additions of montmorillonite nanoparticles in NaOH/urea/thiourea aqueous-alkaline solutions were studied. X-ray diffraction analysis shows that montmorillonite nanoparticles in hydrated cellulose and chitin films are in the intercalated state. Analysis of the Fourier IR spectra of the composite films reveals the shift of the Si–O absorption band in both polymer systems. Introduction of montmorillonite into hydrated cellulose and chitin matrices leads to an increase in the residual weight (at 800°C) and to a slight decrease in the degradation onset temperature and in the temperature of the maximal degradation rate.

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REFERENCES

  1. Zimmermann, T., Bordeanu, N., and Strub, E., Carbohydrate Polym., 2010, vol. 79, no. 4, pp. 1086–1093. https://doi.org/10.1016/j.carbpol.2009.10.045

    Article  CAS  Google Scholar 

  2. Chen, W., Yu, H., Liu, Y., Hai, Y., Zhang, M., and Chen, P., Cellulose, 2011, vol. 18, no. 2, pp. 433–442. https://doi.org/10.1007/s10570-011-9497-z

    Article  CAS  Google Scholar 

  3. Fan, Y., Saito, T., and Isogai, A., Carbohydrate Polym., 2010, vol. 79, no. 4, pp. 1046–1051. https://doi.org/10.1016/j.carbpol.2009.10.044

    Article  CAS  Google Scholar 

  4. Fan, Y., Saito, T., and Isogai, A., Carbohydrate Polym., 2009, vol. 77, no. 4, pp. 832–838. https://doi.org/10.1016/j.carbpol.2009.03.008

    Article  CAS  Google Scholar 

  5. Sorrentino, A., Gorrasi, G., and Vittoria, V., Trends Food Sci. Technol., 2007, vol. 18, no. 2, pp. 84–95. https://doi.org/10.1016/j.tifs.2006.09.004

    Article  CAS  Google Scholar 

  6. Prashanth, K.V.H. and Tharanathan, R.N., Trends Food Sci. Techol., 2007, vol. 18, no. 3, pp. 117–131. https://doi.org/10.1016/j.tifs.2006.10.022

    Article  CAS  Google Scholar 

  7. Melle, J., Mooz, M., and Meister, F., Macromol. Symp., 2006, vol. 244, pp. 166–174. https://doi.org/10.1002/masy.200651215

    Article  CAS  Google Scholar 

  8. Delhom, C.D., White-Ghoorahoo, L.A., and Pang, S.S., Composites: Part B, 2010, vol. B 41, no. 6, pp. 475–481. https://doi.org/10.1016/j.compositesb.2009.10.007

    Article  CAS  Google Scholar 

  9. Bochek, A.M., Zabivalova, N.M., Gofman, I.V., Yudin, V.E., Lavrent’ev, V.K., and Abalov, I.V., Russ. J. Appl. Chem., 2011, vol. 84, no. 7, pp. 1261–1265. https://doi.org/10.1134/S107042721107024X

    Article  CAS  Google Scholar 

  10. Gunister, E., Pestreli, D., Unlu, C.H., Atici, O., and Gungor, N., Carbohydrate Polym., 2007, vol. 67, no. 3, pp. 358–365. https://doi.org/10.1016/j.carbpol.2006.06.004

    Article  CAS  Google Scholar 

  11. Monvisade, P. and Siriphannon, P., Appl. Clay Sci., 2009, vol. 42, nos. 3–4, pp. 427–431. https://doi.org/10.1016/j.clay.2008.04.013

    Article  CAS  Google Scholar 

  12. Darder, M., Colilla, M., and Ruiz-Hitzky, E., Chem. Mater., 2003, vol. 15, no. 20, pp. 3774–3780. https://doi.org/10.1021/cm0343047

    Article  CAS  Google Scholar 

  13. Darder, M., Colilla, M., and Ruiz-Hitzky, E., Appl. Clay Sci., 2005, vol. 28, nos. 1–4, special issue, pp. 199–208. https://doi.org/10.1016/j.clay.2004.02.009

    Article  CAS  Google Scholar 

  14. Han, Y.S., Lee, S.H., Choi, K.H., and Park, I., J. Phys. Chem. Solids, 2010, vol. 71, no. 4, pp. 464–467. https://doi.org/10.1016/j.jpcs.2009.12.012

    Article  CAS  Google Scholar 

  15. Wang, S.F., Shen, L., Tong, Y.J., Chen, L., Phang, I.Y., Lim, P.Q., and Liu, T.X., Polym. Degrad. Stab., 2005, vol. 90, no. 1, pp. 123–131. https://doi.org/10.1016/j.polymdegradstab.2005.03.001

    Article  CAS  Google Scholar 

  16. Xu, Y., Ren, X., and Hanna, M.A., J. Appl. Polym. Sci., 2006, vol. 99, no. 4, pp. 1684–1691. https://doi.org/10.1002/app.22664

    Article  CAS  Google Scholar 

  17. Hu, X., Du, Y., Tang, Y., Wang, Q., Feng, T., Yang, J., and Kennedy, J.F., Carbohydrate Polym., 2007, vol. 70, no. 4, pp. 451–458. https://doi.org/10.1016/j.carbpol.2007.05.002

    Article  CAS  Google Scholar 

  18. Wu, J., Liang, S., Dai, H., Zhang, X., Yu, X., Cai, Y., Zhang, L., Wen, N., Jiang, B., and Xu, J., Carbohydrate Polym., 2010, vol. 79, no. 3, pp. 677–684. https://doi.org/10.1016/j.carbpol.2009.09.022

    Article  CAS  Google Scholar 

  19. Zhang, S., Li, F.X., Yu, J.Y., and Hsieh, Y.L., Carbohydrate Polym., 2010, vol. 81, no. 3, pp. 668–674. https://doi.org/10.1016/j.carbpol.2010.03.029

    Article  CAS  Google Scholar 

  20. Luo, X. and Zhang, L., Food Res. Int., 2013, vol. 52, no. 1, pp. 387–400. https://doi.org/10.1016/j.foodres.2010.05.016

    Article  CAS  Google Scholar 

  21. Yang, Q., Wu, C.N., Saito, T., and Isogai, A., Carbohydrate Polym., 2014, vol. 100, pp. 179–184. https://doi.org/10.1016/j.carbpol.2012.10.044

    Article  CAS  Google Scholar 

  22. Shamolina, I.I., Bochek, A.M., Zabivalova, N.M., Vlasova, E.N., Volchek, B.Z., and Sinitsin, A.P., Russ. J. Appl. Chem., 2004, vol. 77, no. 10, pp. 1729–1732. https://doi.org/10.1007/s11167-005-0106-5

    Article  CAS  Google Scholar 

  23. Terbojevich, M., Carraro, C., Cosani, A., and Morsano, E., Carbohydrate. Res., 1988, vol. 180, no. 1, pp. 73–86. https://doi.org/10.1021/ma00154a010

    Article  CAS  Google Scholar 

  24. Jin, H., Zha, C., and Gu, L., Carbohydrate Res., 2007, vol. 342, no. 6, pp. 851–858. https://doi.org/10.1016/j.carres.2006.12.023

    Article  CAS  Google Scholar 

  25. Hu, X., Tang, Y., Wang, Q., Li, Y., Yang, J., Du, Y., and Kennedy, J.F., Carbohydrate Polym., 2011, vol. 83, no. 3, pp. 1128–1133. https://doi.org/10.1016/j.carbpol.2010.09.014

    Article  CAS  Google Scholar 

  26. Bochek, A.M., Serov, I.V., Novoselov, N.P., Zabivalova, N.M., Lavrent’ev, V.K., Vlasova, E.N., and Volchek, B.Z., Fibre Chem., 2015, vol. 47, no. 3, pp. 166–170. https://doi.org/10.1007/s10692-015-9659-0

    Article  CAS  Google Scholar 

  27. Serov, I.V., Bochek, A.M., Novoselov, N.P., Zabivalova, N.M., Lavrent’ev, V.K., Vlasova, E.N., and Volchek, B.Z., Fibre Chem., 2015, vol. 47, no. 4, pp. 247–250. https://doi.org/10.1007/s10692-016-9673-x

    Article  CAS  Google Scholar 

  28. Bochek, A.M., Zabivalova, N.M., Yudin, V.E., Gofman, I.V., Lavrent’ev, V.K., Volchek, B.Z., Vlasova, E.N., Abalov, I.V., Brusilovskaya, N.G., and Osovskaya, I.I., Polym. Sci., Ser. A, 2011, vol. 53, no. 12, pp. 1167–1174. https://doi.org/10.1134/S0965545X11120029

    Article  CAS  Google Scholar 

  29. Kulichikhin, V.G., Semakov, A.V., Karbushev, V.V., Platé, N.A., and Picken, S.J., Polym. Sci., Ser. A, 2009, vol. 51, nos. 11–12, pp. 1303–1312. https://doi.org/10.1007/s10692-016-9673-x

    Article  Google Scholar 

  30. Yin, H., Mo, D., and Chen, D., J. Polym. Sci., Part B: Polym. Phys., 2009, vol. 47, no. 10, pp. 945–954. https://doi.org/10.1002/polb.21701

    Article  CAS  Google Scholar 

  31. Petrova, V.A., Nud’ga, L.A., Bochek, A.M., Yudin, V.E., Gofman, I.V., Elokhovskii, V.Yu., and Dobrovol’skaya, I.P., Polym. Sci., Ser. A, 2012, vol. 54, no. 3, pp. 224–230. https://doi.org/10.1134/S0965545X1203008X

    Article  CAS  Google Scholar 

  32. Oh, S.Y., Yoo, D.I., Shin, Y., Kim, H.C., Kim, H.Y., Chung, Y.S., Park, W.H., and Youk, J.H., Carbohydrate Res., 2005, vol. 340, no. 15, pp. 2376–2391. https://doi.org/10.1016/j.carres.2005.08.007

    Article  CAS  Google Scholar 

  33. Wu, Y., Sasaki, T., Irie, S., and Sakurai, K., Polymer, 2008, vol. 49, no. 9, pp. 2321–2327. https://doi.org/10.1016/j.polymer.2008.03.027

    Article  CAS  Google Scholar 

  34. Amarasinghe, P.M., Katti, K.S., and Katti, D.R., J. Colloid Interface Sci., 2009, vol. 337, no. 1, pp. 97–105. https://doi.org/10.1016/j.jcis.2009.05.011

    Article  CAS  PubMed  Google Scholar 

  35. Van de Velde, K. and Kiekens, P., Carbohydrate Polym., 2004, vol. 58, no. 4, pp. 409–416. https://doi.org/10.1016/j.carbpol.2004.08.004

    Article  CAS  Google Scholar 

  36. Prabu, K. and Natarajan, E., Adv. Appl. Sci. Res., 2012, vol. 3, no. 2, pp. 1870–1875.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    A. M. Bochek, I. V. Serov, I. L. Shevchuk, V. K. Lavrent’ev, E. N. Popova, E. N. Vlasova, B. Z. Volchek & E. V. Yudin

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Bochek, A.M., Serov, I.V., Shevchuk, I.L. et al. Properties of Solutions of Cellulose and Chitin with Montmorillonite Nanoparticles in Aqueous Alkali with Urea and Thiourea Additions and of Composite Films Prepared from These Solutions. Russ J Appl Chem 93, 572–580 (2020). https://doi.org/10.1134/S1070427220040126

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