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Preparation of a New Material Based on Epoxy Oligomers for Forming Corrosion-Protective Coatings

  • Macromolecular Compounds and Polymeric Materials
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Abstract

New adhesive materials based on a single-part hot-cured epoxy adhesive for forming corrosion-protective coatings were obtained. Perfluoropentanoic acid N-methylpiperazide and polyethylenepolyamine were used as curing catalysts. The adhesive compounds in the cured state were characterized by the degree of swelling, gel fraction content, Vickers hardness, elastic modulus, and creep strain; their corrosion-protective properties with respect to low-carbon steel (St. 3) and aluminum–magnesium alloy (AMg-6) were determined. The chemical structure of the organic solvent and amine curing agent largely determines the operation characteristics of the coatings obtained.

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REFERENCES

  1. Paluvai, N.R., Mohanty, S., and Nayak, S.K., Polym. Plast. Technol. Eng., 2014, vol. 53, no. 16, pp. 1723–1758. https://doi.org/10.1080/03602559.2014.919658

    Article  CAS  Google Scholar 

  2. Lobanov, M.V., Gulyaev, A.I., and Babin, A.N., Polym. Sci., Ser. B, 2016, vol. 58, no. 1, pp. 1–12. https://doi.org/10.1134/S1560090416010048

    Article  CAS  Google Scholar 

  3. Chrusciel, J.J. and Lesniak, E., Prog. Polym. Sci., 2015, vol. 41, pp. 67–121. https://doi.org/10.1016/j.progpolymsci.2014.08.001

    Article  CAS  Google Scholar 

  4. Stuparu, M.C. and Khan, A., J. Polym. Sci. A: Polym. Chem., 2016, vol. 54, no. 19, pp. 3057–3070. https://doi.org/10.1002/pola.28195

    Article  CAS  Google Scholar 

  5. Ding, C. and Matharu, A.S., ACS Sustain. Chem. Eng., 2014, vol. 2, no. 10, pp. 2217–2236. https://doi.org/10.1021/sc500478f

    Article  CAS  Google Scholar 

  6. Hsiue, G.-H., Wei, H.-F., Shiao, S.-J., Kuo, W.-J., and Sha, Y.-A., Polym. Degrad. Stab., 2001, vol. 73, no. 2, pp. 309–318. https://doi.org/10.1016/S0141-3910(01)00092-1

    Article  CAS  Google Scholar 

  7. Sprenger, S., Polymer, 2013, vol. 54, no. 18, pp. 4790–4797. https://doi.org/10.1016/j.polymer.2013.06.011

    Article  CAS  Google Scholar 

  8. Alam, A., Wan, C., and McNally, T., Eur. Polym. J., 2017, vol. 87, pp. 422–448. https://doi.org/10.1016/j.eurpolymj.2016.10.004

    Article  CAS  Google Scholar 

  9. Sinh, L.H., Son, B.T., Nguyen, N., Lim, D.-G., Shin, S., and Bae, J.-Y., React. Funct. Polym., 2012, vol. 72, no. 8, pp. 542–548. https://doi.org/10.1016/j.reactfunctpolym.2012.05.004

    Article  CAS  Google Scholar 

  10. Efimov, A.A., Zagidullin, A.I., Kolpakova, M.V., Garipov, R.M., and Stoyanov, O.V., Klei. Germet. Tekhnol., 2008, no. 4, pp. 12–17.

    Google Scholar 

  11. Sytov, V.A., Verstakov, A.E., Voronin, A.E., and Sytov, V.V., Polym. Sci., Ser. D, 2013, vol. 6, no. 2, pp. 116–119. https://doi.org/10.1134/S1995421213020147

    Article  CAS  Google Scholar 

  12. Patel, H. and Patel, B.K., Int. J. Polym. Mater., 2009, vol. 58, no. 6, pp. 312–321. https://doi.org/10.1080/00914030902859257

    Article  CAS  Google Scholar 

  13. Stroganov, V.F. and Stroganov, I.V., Polym. Sci., Ser. D, 2016, vol. 9, no. 2, pp. 141–144. https://doi.org/10.1134/S1995421216020222

    Article  CAS  Google Scholar 

  14. Hickey, D.P., Halmes, A.J., Schmidtke, D.W., and Glatzhofer, D.T., Electrochim. Acta, 2014, vol. 149, no. 1, pp. 252–257. https://doi.org/10.1016/j.electacta.2014.10.077

    Article  CAS  Google Scholar 

  15. Derouet, D., Morvan, F., and Brosse, J.C., J. Appl. Polym. Sci., 1996, vol. 62, no. 11, pp. 1855–1868.

    Article  CAS  Google Scholar 

  16. Wang, Y., Li, H., Wang, X., Lei, H., and Huo, J., RSC Adv., 2016, vol. 6, no. 87, pp. 84187–84193. https://doi.org/10.1039/C6RA18347F

    Article  CAS  Google Scholar 

  17. Chen, M.-A., Xie, X., and Zhang, X.-M., Prog. Org. Coat., 2009, vol. 66, no. 1, pp. 40–51. https://doi.org/10.1016/j.porgcoat.2009.05.003

    Article  CAS  Google Scholar 

  18. Hu, H.P., Gilbert, R.D., and Fornes, R.E., J. Polym. Sci. A: Polym. Chem., 1987, vol. 25, no. 5, pp. 1235–1248. https://doi.org/10.1002/pola.1987.080250504

    Article  CAS  Google Scholar 

  19. Pestov, A.V., Puzyrev, I.S., Mekhaev, A.V., Gorbunova, T.I., Saloutin, V.I., Smirnov, S.V., Vichuzhanin, D.I., and Matafonov, P.P., Russ. J. Appl. Chem., 2014, vol. 87, no. 4, pp. 474–479. https://doi.org/10.1134/S10704272140400132

    Article  CAS  Google Scholar 

  20. Suvorov, A.L., Dul’tseva, L.D., Ovchinnikova, G.I., Yatluk, Yu.G., and Alekhina, V.D., Plast. Massy, 1989, no. 3, pp. 95–96.

    Google Scholar 

  21. Pestov, A.V., Kuznetsov, V.A., Mekhaev, A.V., Gorbunova, T.I., Saloutin, V.I., Smirnov, S.V., Vichuzhanin, D.I., and Matafonov, P.P., Polym. Sci., Ser. D, 2015, vol. 8, no. 2, pp. 149–152. https://doi.org/10.1134/S1995421215020136

    Article  CAS  Google Scholar 

  22. Suvorov, A.L., Dul’tseva, L.D., Ovchinnikova, G.I., Khrustaleva, E.A., Ostanina, N.Yu., and Abramova, V.I., Russ. J. Appl. Chem., 2003, vol. 76, no. 11, pp. 1844–1849. https://doi.org/10.1023/B:RJAC.0000018697.76047.67

    Article  CAS  Google Scholar 

  23. Gorbunova, T.I., Bazhin, D.N., Zapevalov, A.Ya., and Saloutin, V.I., Russ. J. Appl. Chem., 2013, vol. 86, no. 7, pp. 992–996. https://doi.org/10.1134/S1070427213070082

    Article  CAS  Google Scholar 

  24. Lipatov, Yu.S., Fiziko-khimicheskie osnovy napolneniya polimerov (Physicochemical Principles of Polymer Filling), Moscow: Khimiya, 1991.

    Google Scholar 

  25. Smirnov, S.V., Veretennikova, I.A., Smirnova, E.O., and Pestov, A.V., Diagn., Resource Mech. Mater. Struct., 2017, no. 6, pp. 103–111. https://doi.org/10.17804/2410-9908.2017.6.103-111

    Article  Google Scholar 

  26. Postnikova, I.I., Sinel’nikova, L.N., Yatluk, Yu.G., Khrustaleva, E.A., and Suvorov, A.L., Zh. Obshch. Khim., 1992, vol. 62, no. 1, pp. 36–38.

    CAS  Google Scholar 

  27. Fedoseev, M.S., Derzhavinskaya, L.F., Karmanov, V.I., Bazhin, D.N., Zapevalov, A.Ya., Gorbunova, T.I., and Saloutin, V.I., Russ. J. Appl. Chem., 2010, vol. 83, no. 4, pp. 723–727. https://doi.org/10.1134/S1070427210040270

    Article  CAS  Google Scholar 

  28. Minisini, B., Rolère, S., Coulon, J.-F., and Poncin-Epaillard, F., Eur. Polym. J., 2019, vol. 112, pp. 452–460. https://doi.org/10.1016/j.eurpolymj.2019.01.035

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 620108, Yekaterinburg, Russia

    A. V. Pestov, V. A. Osipova, O. V. Koryakova & T. I. Gorbunova

  2. Institute of Engineering Science, Ural Branch, Russian Academy of Sciences, 620108, Yekaterinburg, Russia

    S. V. Smirnov & I. A. Veretennikova

Authors
  1. A. V. Pestov
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  2. V. A. Osipova
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  3. O. V. Koryakova
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  4. T. I. Gorbunova
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  5. S. V. Smirnov
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  6. I. A. Veretennikova
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Corresponding author

Correspondence to A. V. Pestov.

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FUNDING

The mechanical properties were studied within the framework of Russian Science Foundation project no. 19-19-00571 (in the part of studying the coating of polyethylenepolyamine-cured ETP adhesive) and of the government assignment for the Institute of Engineering Science, Ural Branch, Russian Academy of Sciences using the equipment of the Plastometry Center for Shared Use. The compound preparation and characterization of the corrosion-protective properties were performed within the framework of the government assignment for the Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences using the equipment of the Center for Shared Use “Spectroscopy and Analysis of Organic Compounds.”

CONFLICT OF INTERESTS

The authors declare that they have no conflict of interest.

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Pestov, A.V., Osipova, V.A., Koryakova, O.V. et al. Preparation of a New Material Based on Epoxy Oligomers for Forming Corrosion-Protective Coatings. Russ J Appl Chem 93, 400–405 (2020). https://doi.org/10.1134/S107042722003012X

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  • DOI: https://doi.org/10.1134/S107042722003012X

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