Abstract
A method was proposed for producing ZnS semiconductor nanoparticles: “quantum dots” in an ionic liquid medium, N-decylpyridinium tetrafluoroborate. The average nanoparticle sizes were determined by UV spectroscopy, dynamic light scattering, and probe microscopy. It is shown that a high threshold concentration of nanoparticles is reached in the ionic liquid medium, an increase in the concentration of precursors in the reaction mixture leads to an increase in the average size of nanoparticles. Ultrasonic treatment helps to reduce the polydispersity of sols and results in the formation of stable sols with a higher concentration of nanoparticles.
Similar content being viewed by others
REFERENCES
Grainger, D.W. and Castner, D.J., Adv. Mater., 2008, vol. 20, pp. 867–877. https://doi.org/10.1002/adma.200701760
Baer, D.R., J. Vacuum Sci. & Technol. A, 2013, vol. 31, no. 5, p. 50820. https://doi.org/10.1116/1.4818423
Baer, D.R., Gaspar, D.J., Nachimuthu, P., Techane, S.D., and Castner, D.G., Anal. Bioanal. Chem., 2010, vol. 396, pp. 983–1002. https://doi.org/10.1007/s00216-009-3360-1
Alivisatos, P., Nat. Biotechnol., 2004, vol. 22, pp, 47–52. https://doi.org/10.1038/nbt927
Michalet, X., Pinaud, F.F., Bentolila, L.A., Tsay, J.M., Doose, S., Li, J.J., Sundaresan, G., Wu, A.M., Gambhir, S.S., and Weiss, S., Science, 2005, vol. 307, pp. 538–544. https://doi.org/10.1126/science.1104274
Zorn, G., Dave, S.R., Gao, X., and Castner, D.G., Anal. Chem., 2011, vol. 83, pp. 866–873. https://doi.org/10.1021/Ac102516n
Morris-Cohen, A.J., Malicki, M., Peterson, M.D., Slavin, J., W.J., and Weiss, E.A., Chem. Mater., 2013, vol. 25, no. 8, pp. 1155–1165. https://doi.org/10.1021/cm302108j
Smith, A.M. and Nie, S.M., Analyst, 2004, vol. 129, pp. 672–677. https://doi.org/10.1039/b404498n
Medintz, I.L., Uyeda, H.T., Goldman, E.R., and Mattoussi, H., Nat. Mater., 2005, vol. 4, no. 6, pp. 435–446. https://doi.org/10.1038/nmat1390
Murray, C.B., Norris, D.J., and Bawendi, M.G., J. Am. Chem. Soc., 1993, vol. 115, pp. 8706–8715. https://doi.org/10.1021/ja00072a025
Joo, J., Na, H.B., Yu, T., Yu, J.H., Kim, Y.W., Wu, F., Zhang, J.Z., and Hyeon, T., J. Am. Chem. Soc., 2003, vol. 125, pp. 11100–11105. https://doi.org/10.1021/ja0357902
Wang, G.Z., Geng, B.Y., Huang, X.M., Wang, Y.W., Li, G.H., and Zhang, L.D., Appl. Phys. A, 2003, vol. 77, pp. 933–936. https://doi.org/10.1007/s00339-002-2033-0
Wang, L.P. and Hong, G.Y., Mater. Res. Bull., 2000, vol. 35, pp. 695–701. https://doi.org/10.1016/S0025-5408(00)00261-0
Dash, P. and Scott, R.W.J., Mater. Lett., 2011, vol. 65, pp. 7–9. https://doi.org/10.1016/j.matlet.2010.09.031
Dupont, J., Fonseca, G.S., Umpierre, A.P., Fichtner, P.F.P., and Teixeira, S.R., J. Am. Chem. Soc., 2002, vol. 124, no. 16, pp. 4228–4229. https://doi.org/10.1021/ja025818u
Richter, K., Campbell, P.S., Baecker, T., Schimitzek, A., Yaprak, D., and Mudring, A.V., Phys. Status Solidi B, 2013, vol. 250, pp. 1152–1164. https://doi.org/10.1002/pssb.201248547
Yin, S., Luo, Z., Xia, J., and Li, H., J. Phys. Chem. Solids, 2010, vol. 71, pp. 1785–1788. https://doi.org/10.1016/j.jpcs.2010.09.016
Zhuravlev, O.E., Presnyakov, I.A., and Voronchikhina, L.I., Russ. J. Appl. Chem., 2015, vol. 88, no. 6, pp. 914–920. https://doi.org/10.1134/S1070427215060038?
Zhilenko, M.P., Lupandina, K.V., Ehrlich, H.V., and Lisichkin, G.V., Russ. Chem. Bull., 2010, vol. 59, no. 7, pp. 1307–1311. https://doi.org/10.1007/s11172-010-0239-4?
Manukumar, K.N., Nagaraju, G., Kishore Brij Madhu, C., and Munichandraiah, N., J. Energy Chem., 2018, vol. 27, no. 3, pp. 806–812. https://doi.org/10.1016/j.jechem.2017.05.010
Spravochnik khimika, T. 6 (Handbook of a Chemist, vol. 6), Nikol’skii, V.P., Ed., Leningrad: Khimiya, 1966.
Bolotov, A.N., Novikov, V.V., and Novikova, O.O., Izv. Vuzov. Khimiya Khim. Tekhnologiya, 2017, vol. 60, no. 4, pp. 75–81. https://doi.org/10.6060/tcct.2017604.5506
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
FUNDING
The study was carried out with financial support from the Russian Foundation for Basic Research in the framework of the scientific project no. 18-33-00890.
CONFLICT OF INTERESTS
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Zhuravlev, O.E., Krotova, N.I. & Voronchikhina, L.I. Influence of Concentration of Precursors and Solvent on the Size of Zinc Sulfide Nanoparticles Produced in Ionic Liquid Medium. Russ J Appl Chem 93, 340–345 (2020). https://doi.org/10.1134/S1070427220030040
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427220030040