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Thermal Conductivity of Calcium Aluminate and Complex Vanadates of Garnet Structure

  • Physicochemical Studies of Systems and Processes
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Abstract

The thermal conductivity of materials with the nonstoichiometric garnet structure, namely, of calcium aluminate Са12Al14O33±δ (both single crystal and ceramic) and doped vanadates Ca5Mg4–xMx(VO4)6 (M = Zn, Co; 0 ≤ x ≤ 4), in the temperature interval 50–300 K was studied by the steady state comparative-longitudinal thermal flux method. The compositions Ca5Mg4–xZnx(VO4)6, x =1, 3, 4, were studied in the temperature interval 298–573 K by the dynamic method. The effect of the defective structure on the thermal conductivity of the materials was discussed. The thermal conductivity of the materials is ~2 W m–1 K–1 at room temperature and above.

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Authors and Affiliations

  1. Ural Federal University, 620002, Yekaterinburg, Russia

    A. S. Tolkacheva & S. N. Shkerin

  2. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    A. S. Tolkacheva & S. N. Shkerin

  3. Petrovsky Bryansk State University, 241036, Bryansk, Russia

    P. A. Popov & A. A. Krugovykh

  4. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    S. V. Naumov

  5. University of Information Technologies, Mechanics, and Optics, 197101, St. Petersburg, Russia

    P. D. Khavlyuk

  6. Lobachevsky State University, 603950, Nizhny Novgorod, Russia

    S. V. Telegin

Authors
  1. A. S. Tolkacheva
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  2. P. A. Popov
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  3. S. N. Shkerin
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  4. S. V. Naumov
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  5. P. D. Khavlyuk
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  6. A. A. Krugovykh
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  7. S. V. Telegin
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Corresponding author

Correspondence to A. S. Tolkacheva.

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FUNDING

The study was performed using the equipment of the Center for Shared Use at the Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences. The single crystal of mayenite was grown within the framework of Spin program of the Federal Agency of Scientific Organizations of the Russian Federation, no. АААА-А18-118020290104-2. The study was financially supported in part by the Russian Foundation for Basic Research (project no. 17-03-01280_а).

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The authors declare that they have no conflict of interest.

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Tolkacheva, A.S., Popov, P.A., Shkerin, S.N. et al. Thermal Conductivity of Calcium Aluminate and Complex Vanadates of Garnet Structure. Russ J Appl Chem 93, 325–332 (2020). https://doi.org/10.1134/S1070427220030027

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