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Selective Hydrogenation of Phenylacetylene on a Pd-Containing Catalyst Based on a Polymer Layered Substrate

  • Catalysis
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Abstract

A Pd-containing catalyst based on a layered substrate obtained by the polymerization of 2,3,6,7,10,11-hexahydroxytriphenylene and terephthalic aldehyde was developed and studied. The process of liquid-phase hydrogenation of phenylacetylene was studied on the obtained catalyst. It was found that high selectivity for styrene (97%) with complete phenylacetylene conversion is achieved at a hydrogen pressure of 0.1 MPa and a temperature of 40˚C. It has been shown that the catalyst exhibits high stability—maintaining conversion and selectivity for 6 cycles.

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Authors and Affiliations

  1. Lomonosov Moscow State University, 119991, Moscow, Russia

    I. I. Shakirov, M. P. Boronoev, N. A. Sinikova, E. A. Karakhanov & A. L. Maksimov

  2. Topchiev Institute of Petrochemical Synthesis of Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maksimov

Authors
  1. I. I. Shakirov
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  2. M. P. Boronoev
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  3. N. A. Sinikova
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  4. E. A. Karakhanov
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  5. A. L. Maksimov
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Correspondence to I. I. Shakirov.

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FUNDING

The study was funded by a grant from the Russian Foundation for Basic Research (project no. 18-33-00987).

CONFLICT OF INTERESTS

Co-author A.L. Maksimov claims to be the editor-in-chief of the Journal of Applied Chemistry; the remaining co-authors have no conflict of interest.

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Shakirov, I.I., Boronoev, M.P., Sinikova, N.A. et al. Selective Hydrogenation of Phenylacetylene on a Pd-Containing Catalyst Based on a Polymer Layered Substrate. Russ J Appl Chem 93, 258–267 (2020). https://doi.org/10.1134/S1070427220020159

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