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Co-Processing of Straight Run Gas Oil-Rapeseed Oil Mixture Using Sulfide NiMo Catalyst on Zeolite-Containing Support

  • Catalysis
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Abstract

Behavior of the sulfide NiMo catalyst on an alumina support containing SAPO—11 silicoaluminophosphate (NiMo/SAP-Al2O3) in the hydroprocessing of a mixture of a straight run gas oil (SRGO) and rapeseed oil (RO) was studied under a pressure of 5.0 MPa and liquid hourly space velocity of 1.5 h−1. The effect of temperature on the properties of the products produced in the hydroprocessing of a mixture with 30 wt % RO and 70 wt % SRGO in the presence of the NiMo/SAP-Al2O3 catalyst and a double-bed catalytic system containing layer-by-layer loaded Mo/Al2O3 and NiMo/SAP-Al2O3 sulfide catalysts. It was found that the experimental conditions provide a full conversion of oxygen-containing compounds and reduction of the content of sulfur to less than 10 mg kg−1. Raising the temperature from 330 to 380°C leads to an increase in the conversion of alkanes formed due to the hydrodeoxygenation of rapeseed oil and to lowering of the cloud point of the hydroprocessing products by approximately 15°. Possible reasons for the differences in behavior between the systems under study: a high conversion of C17, C18 alkanes is reached in the presence of the NiMo/SAP-Al2O3 catalyst, whereas the double layer Mo/Al2O3 + NiMo/SAP-Al2O3 system provides a more effective course of the reactions in which aromatic hydrocarbons are hydrogenated.

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Acknowledgments

The authors are grateful to E.Yu. Gerasimov for a TEM analysis of samples of the sulfide catalysts. The study was carried out on the equipment of the Collective Use Center “National center of research into catalysts.”

Funding

The study was financially supported by the Ministry of Science and Higher Education of the Russian Federation, project no. 14.575.21.0128, unique project identifier RFMEFI57517X0128.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. A. Porsin, E. N. Vlasova, A. L. Nuzhdin, P. V. Aleksandrov & G. A. Bukhtiyarova

  2. Novosibirsk National Research State University (NGU), Novosibirsk, 630090, Russia

    E. N. Vlasova, P. V. Aleksandrov & G. A. Bukhtiyarova

Authors
  1. A. A. Porsin
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  2. E. N. Vlasova
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  3. A. L. Nuzhdin
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  4. P. V. Aleksandrov
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  5. G. A. Bukhtiyarova
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Corresponding author

Correspondence to E. N. Vlasova.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 13, pp. 1723–1731.

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Porsin, A.A., Vlasova, E.N., Nuzhdin, A.L. et al. Co-Processing of Straight Run Gas Oil-Rapeseed Oil Mixture Using Sulfide NiMo Catalyst on Zeolite-Containing Support. Russ J Appl Chem 92, 1797–1804 (2019). https://doi.org/10.1134/S1070427219120228

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