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Isomerization of Linear Paraffin Hydrocarbons in the Presence of Sulfide CoMo and NiW Catalysts on Al2O3—SAPO-11 Support

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Abstract

Supported CoMoS and NiWS catalysts were synthesized on the basis of an Al2O3—SAPO-11 composite support. The acid and texture characteristics of the thus synthesized materials were examined. The morphologies of the active sulfide phase of the catalysts were compared. The kinetic properties of the supported sulfide catalysts in the reaction of hydroisomerization of n-hexadecane and in the hydroprocessing of the diesel fraction were examined. It was shown that it is possible to obtain hydrogenates with improved low-temperature properties in the presence of supported sulfide catalysts containing no noble metals.

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Acknowledgments

The authors wish to thank A.V. Mozhaev, Cand. Sci. (Chem.), researcher in the Chair of CHemical Technology of Oil and Gas Refining in SSTU (Samara) for assistance in studies by the methods of temperature-programmed desorption of ammonia and low-temperature adsorption of nitrogen.

The authors are grateful to the Collective Use Center “Advanced technologies and analytics of nanosystems” at Novosibirsk State University for performing analyses by the method of high-resolution transmission electron microscopy.

Funding

The study was financially supported by the ministry of Science and Higher Education of the Russian Federation, project no. 14.574.21.0139 (unique project identifier RFMEFI 57417X0139).

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Authors and Affiliations

  1. Samara State Technical University, Samara, 443100, Russia

    Al. A. Pimerzin, A. A. Savinov, D. I. Ishutenko, S. P. Verevkin & A. A. Pimerzin

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  1. Al. A. Pimerzin
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  2. A. A. Savinov
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  3. D. I. Ishutenko
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  4. S. P. Verevkin
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Correspondence to Al. A. Pimerzin.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 13, pp. 1695–1703.

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Pimerzin, A.A., Savinov, A.A., Ishutenko, D.I. et al. Isomerization of Linear Paraffin Hydrocarbons in the Presence of Sulfide CoMo and NiW Catalysts on Al2O3—SAPO-11 Support. Russ J Appl Chem 92, 1772–1779 (2019). https://doi.org/10.1134/S1070427219120198

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