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Water-Soluble Metal—Polymer Gallium Complexes Based on Imino Derivatives of an N-Vinylpyrrolidone/N-Vinylamine Copolymer

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Abstract

Imino derivatives of salicylic aldehyde and a N-vinylpyrrolidone/N-vinylamine containing 15 mol % N-vinyl salicylidenimine were synthesized. Water-soluble metal—polymer complexes with a gallium content of 5 mol % were obtained by the interaction of imino derivatives with gallium(III) chloride. The structure and composition of the metal—polymer complex are confirmed by electron, vibrational, atomic emission spectroscopy with inductively coupled plasma, and by nuclear magnetic resonance spectroscopy.

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Funding

This work was financially supported by the Russian Science Foundation, grant no. 18-13-00324.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, 199004, Russia

    A. G. Ivanov, I. I. Gavrilova, V. D. Krasikov & E. F. Panarin

Authors
  1. A. G. Ivanov
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  2. I. I. Gavrilova
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  3. V. D. Krasikov
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  4. E. F. Panarin
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Corresponding author

Correspondence to A. G. Ivanov.

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The authors declare that there is no conflict of interest requiring disclosure in this article; co-author E.F. Panarin is deputy editor-in-chief of the Journal of Applied Chemistry.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 13, pp. 1666–1672.

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Ivanov, A.G., Gavrilova, I.I., Krasikov, V.D. et al. Water-Soluble Metal—Polymer Gallium Complexes Based on Imino Derivatives of an N-Vinylpyrrolidone/N-Vinylamine Copolymer. Russ J Appl Chem 92, 1705–1711 (2019). https://doi.org/10.1134/S1070427219120113

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  • DOI: https://doi.org/10.1134/S1070427219120113

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