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Influence Exerted by Cross-Linking Effect on Properties of Sorbents Produced from Aspen and Larch Bark

  • Sorption and Ion Exchange Processes
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Abstract

Method is suggested for obtaining biochar materials by treatment of a finely dispersed (≤0.1 mm) bark of aspen and(or) larch with a 40% formaldehyde solution and subsequent thermal activation of the activated bark. It was found that keeping the composite at a temperature of 50–80°C for three days makes the binding process complete. Further carbonization at temperatures of 350–900°C yields a biochar with bulk structure. The method of IR spectroscopy confirmed that the functional composition of bark changes under the action of a cross-linking agent and — CH2 — bonds are additionally formed. It was found that the larch bark containing lignins of predominantly G-type and condensed tannins is more suitable for obtaining porous biochar materials (with specific surface area of 94–161 m2 g−1) as compared with the aspen bark. The adsorption properties of biochar materials produced from the modified bark in removal of Cu(II) ions from aqueous solutions. It was found that, on being carbonized at 900°C, a sample of modified aspen bark can extract 122.9 to 220 mg g−1 of copper compounds on raising the sorption temperature from 25 to 45°C.

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References

  1. Kuznetsov, B.N., Levdanskii, V.A., and Kuznetsova, S.A., Khimicheskieprodukty iz drevesnoi kory (Chemical Products from Wood Bark), Krasnoyarsk: Sib. Feder. Univ., 2012, pp. 51–103.

    Google Scholar 

  2. Ivanova, S.Z., Fedorova, T.E., Ivanova, N.V., Ostroukhova, L.A., Malkov, Yu.A., and Babkin, V.A., Khvoinye Boreal’n. Zony, 2003, no. 1, pp. 123–128.

  3. Deineko, I.P. and Faustova, N.M., Khim. Rastit. Syr’ya, 2015, no. 1, pp. 51–62. https://doi.org/10.14258/jcprm.201501461

  4. Tsvetkov, M.V and Salganskii, E.A., Russ. J. Appl. Chem., 2018, vol. 91, no. 7, pp. 1129–1136. https://doi.org/10.1134/S1070427218070108.

    Article  CAS  Google Scholar 

  5. Pizzi, A., Tannins: Major Sources, Properties and Applications in Monomers, Polymers and Composites from Renewable Resources, Belgacem, M.N. and Gandini,A., Eds., Elsevier, 2008, pp. 179–199.

  6. Varfolomeev, A.A., Sinegibskaya, A.D., Gogotov, A.F., Kanitskaya, L.V., and Rokhin, A.V., Khim. Rastit. Syr’ya, 2009, no. 3, pp. 11–16.

  7. Grishechko, L.I., Amaral-Labat, G., Szczurek, A., Fierro, V., Kuznetsov, B.N., and Celzard, A., Micropor. Mesopor. Mater., 2013, vol. 168, pp. 19–29. https://doi.org/10.1016/j.micromeso.2012.09.024

    Article  CAS  Google Scholar 

  8. Tejado, A., Peña, C., Labidi, J., Echeverria, J.M., and Mondragon, I., Bioresour. Technol., 2007, vol. 98, pp. 1655–1663. https://doi.org/10.1016/j.biortech.2006.05.042

    Article  CAS  Google Scholar 

  9. Mikova, N.M., Grishechko, L.I., Skvortsova, G.P., and Kuznetsov, B.N., Russ. J. Bioorg. Chem., 2018, vol. 44, no. 7, pp. 737–745. https://doi.org/10.14258/jcprm.2017041840].

    Article  Google Scholar 

  10. Grishechko, L.I., Amaral-Labat, G., Szczurek, A., Fierro, V., Kuznetsov, B.N., Pizzi, A., and Celzard, A., Ind. Crops Prod., 2013, vol. 41, pp. 347–355. https://doi.org/10.1016/jindcrop.2012.04.052

    Article  CAS  Google Scholar 

  11. Kolosov, P. V., Markin, V.I., Bazarnova, N.G., Ol’khov, Yu.A., and Generalova, E.N., Khim. Rastit. Syr’ya, 2008, no. 3, pp. 55–58.

  12. Kolosov, P.V, Markin, V.I., Bazarnova, N.G., Yusupov, V.R., and Generalova, E.N., Khim. Rastit. Syr’ya, 2009, no. 3, pp. 39–42.

  13. Sizmur, T., Fresno, T., Akgül, G., Frost, H., and Moreno-Jiménez, E., Bioresour. Technol., 2017, vol. 246, pp. 34–47. https://doi.org/10.1016/j.biortech.2017.07.082

    Article  CAS  Google Scholar 

  14. Rajapaksha, A.U., Chen, S.S., Tsang, D.C., Zhang, M., Vithanage, M., Mandal, S., Gao, B., Bolan, N.S., and Ok, Y.S., Chemosphere, 2016, vol. 148, no. 27, pp. 276–291. https://doi.org/10.1016/j.chemosphere.2016.01.043

    Article  CAS  Google Scholar 

  15. Tan, X., Liu, Y., Zeng, G., Wang, X., Hu, X., Gu, Y., and Yang, Z., Chemosphere, 2015, vol. 125, pp. 70–85. https://doi.org/10.1016/j.chemosphere.2014.12.058

    Article  CAS  Google Scholar 

  16. Nwabanne, J. and Igbokwe, P.K., Int. J. Multidisciplinary Sci. Eng., 2012, vol. 3, no. 7, pp. 46–52.

    Google Scholar 

  17. Milenković, D.D., Milosavljević, M.M., Marinković, A.D., Dokić, V.R., Mitrović, J.Z., and Bojić, A.L., Water SA, 2013, vol. 39, no. 4, pp. 515–522. https://doi.org/10.4314/wsa.v39i4.10

    Google Scholar 

  18. Guo, Y. and Rockstraw, D.A., Carbon, 2006, vol. 44, pp. 1464–1475. https://doi.org/10.1016/j.carbon.2005.12.002

    Article  CAS  Google Scholar 

  19. Kriaa, A., Hamdi, N., and Srasra, E., Desalination, 2010, vol. 250, no. 1, pp. 179–187. https://doi.org/10.1016/j.desal.2008.12.056

    Article  CAS  Google Scholar 

  20. Bouhamed, F., Elouear, Z., and Bouzid, J., J. Taiwan Inst. Chem. Eng., 2012, vol. 43, pp. 741–749. https://doi.org/10.1016/j.jtice.2012.02.011

    Article  CAS  Google Scholar 

  21. Tounsadi, H., Khalidi, A., Machrouhi, A., Farnane, M., Elmoubarki, R., Elhalil, A., Sadiq, M., and Barka, N., J. Environ. Chem. Eng., 2016, vol. 4, pp. 4549–4564. https://doi.org/10.1016/j.jece.2016.10.020

    Article  CAS  Google Scholar 

  22. Ostroukhova, L.A., Fedorova, T.E., Onuchina, N.A., Levchuk, A.A., and Babkin, V.A., Khim. Rastit. Syr’ya, 2018, no. 4, pp. 185–195. https://doi.org/10.14258/jcprm.2018044245

  23. Podchainova, V.N. and Simonova, L.N., Analiticheskaya khimiya elementov. Med’ (Analytical Chemistry of Elements. Copper), Moscow: Nauka, 1990, pp. 78–79.

    Google Scholar 

  24. Szczurek, A., Amaral-Labat, G., Fierro, V., Pizzi, A., and Celzard, A., Carbon, 2011, vol. 49, no. 8, pp. 2785–2794. https://doi.org/10.1016/j.carbon.2011.03.005

    Article  CAS  Google Scholar 

  25. Wang, M., Leitch, M., and Xu, Ch.Ch., Eur. Polym. J., 2009, vol. 45, pp. 3380’3388. https://doi.org/10.1016/j.eurpolymj.2009.10.003

    Google Scholar 

  26. Gao, N., Li, A., Quan, C., Du, L., and Duan, Y., J. Anal. Appl. Pyrolysis, 2013, vol. 100, pp. 26–32. https://doi.org/10.1016/jjaap.2012.11.009

    Article  CAS  Google Scholar 

  27. Kuznetsov, B.N., Levdanskii, V.A., Kedrova, L.K., Es’kin, A.P., Polezhaeva, N.I., Safonova, L.V., and Pavlenko, N.I., Khim. Rastit. Syr’ya, 1998, no. 3, pp. 5–12.

  28. Goncharova, N.V., Tok, M.V., and Ryazanova, T. V., Khim. Rastit. Syr’ya, 1998, no. 2, pp. 75–78.

  29. Mikova, N.M., Fetisova, O.Yu., Ivanov, I.P., Pavlenko, N.I., and Chesnokov, N.V., Khim. Rastit. Syr’ya, 2017, no. 4, pp. 53–64. https://doi.org/10.14258/jcprm.2017042018

  30. Parajuli, D., Inoue, K., Ohto, K., Oshima, T., Murota, A., Funaoka, M., and Makino, K., React. Funct. Polym., 2005

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Acknowledgments

The study was carried out on the equipment of the Krasnoyarsk regional collective use center, Siberian Branch, Russian Academy of Sciences.

Funding

The study was carried out under the State assignment to the Institute of Chemistry and Chemical Technology in accordance with the Program of fundamental research by State academies of sciences in the basic research avenue V.46.4.2, project no. 0356-2019-0032.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Krasnoyarsk Federal Research Center, Krasnoyarsk, 660036, Russia

    N. M. Mikova, G. P. Skvortsova, E. V. Mazurova & N. V. Chesnokov

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  1. N. M. Mikova
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  2. G. P. Skvortsova
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  3. E. V. Mazurova
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  4. N. V. Chesnokov
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Correspondence to N. M. Mikova.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 10, pp. 1333–1343.

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Mikova, N.M., Skvortsova, G.P., Mazurova, E.V. et al. Influence Exerted by Cross-Linking Effect on Properties of Sorbents Produced from Aspen and Larch Bark. Russ J Appl Chem 92, 1422–1431 (2019). https://doi.org/10.1134/S1070427219100124

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  • DOI: https://doi.org/10.1134/S1070427219100124

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