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Influence of the Pore Structure of a Catalyst for Demetallization of Petroleum Feedstock on the Process Results

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Abstract

Demetallization of a mixture of vacuum gas oil with heavy coker gas oil on CoMo/γ-Al2O3 catalysts with different pore structures was studied, and the influence of the catalyst pore structure on the process results was demonstrated. For the demetallization catalysts to be effective, their pore size should be restricted not only from below but also from above. When using samples with broad pores, effects of the hydrodesulfurization and hydrodemetallization inhibition can arise owing to adsorption of supramolecular structures of heavy residues, in particular, of asphaltenes.

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References

  1. Kressmann, S., Morel, F., Harlé, V., and Kasztelan, S., Catal. Today, 1998, vol. 43, pp. 203–215. https://doi.org/10.1016/S0920-5861(98)00149-7

    Article  CAS  Google Scholar 

  2. Leyva, C., Rana, M.S., Trejo, F., and Ancheyta, J., Ind. Eng. Chem. Res., 2007, vol. 46, pp. 7448–7466. https://doi.org/10.1021/ie070128q

    Article  CAS  Google Scholar 

  3. Douwes, C.Th., Van Klinken, J., Wijffels, J.B., and Langhout, C., Proc. 10th World Petroleum Congr., 1980, vol. 4, p. 175.

    Google Scholar 

  4. Centeno, G., Ancheyta, J., Alvarez, A., Marroquín, G., Alonso, F., and Castillo, A., Fuel, 2012, vol. 100, pp. 73–79. https://doi.org/10.1016/j.fuel.2012.01.027

    Article  CAS  Google Scholar 

  5. Galiasso, R., Blanco, R., Gonzalez, C., and Quinteros, N., Fuel, 1983, vol. 62, pp. 817–822. https://doi.org/10.1016/0016-2361(83)90034-0

    Article  CAS  Google Scholar 

  6. Toulhoat, H., Plumail, J.C., Martino, G., and Jacquin, Y., Prepr. Am. Chem. Soc., Div. Petrol. Chem., 1985, vol. 30, pp. 85–95.

    CAS  Google Scholar 

  7. De Bruijn, A., Naka, I., and Sonnemans, J.W.M., Ind. Eng. Chem. Process Des. Dev., 1981, vol. 20, p. 40. https://doi.org/10.1021/i200012a005

    Article  CAS  Google Scholar 

  8. Tarakanov, G.V. and Nurakhmedova, A.F., Chem. Technol. Fuels Oils, 2007, vol. 43, pp. 524–530. https://doi.org/10.1007/s10553-007-0092-9

    Article  CAS  Google Scholar 

  9. Furimsky, E., Appl. Catal. A: General, 1998, vol. 171, pp. 177–206. https://doi.org/10.1016/S0926-860X(98)00086-6

    Article  CAS  Google Scholar 

  10. Tarakanov, G.V., Nurakhmedova, A.F., Ramazanova, A.R., and Savenkova, I.V., Neftepererab. Neftekhim., 2016, no. 10, pp. 8–11.

  11. Magomedov, R.N., Popova, A.Z., Maryutina, T.A., Kadiev, Kh.M., and Khadziev, S.N., Petrol. Chem., 2015, vol. 55, pp. 423–443. https://doi.org/10.1134/S0965544115060092

    Article  CAS  Google Scholar 

  12. Farhat Ali, M. and Abbas, S., Fuel Process. Technol., 2006, vol. 87, pp. 573–584. https://doi.org/10.1016/j.fuproc.2006.03.001

    Article  Google Scholar 

  13. Furimsky, E. and Massoth, F.E., Catal. Today, 1999, vol. 52, pp. 381–495. https://doi.org/10.1016/S0920-5861(99)00096-6

    Article  CAS  Google Scholar 

  14. Gulyaeva, L.A., Khavkin, V.A., Shmel’kova, O.I., and Vinogradova, N.Y., Chem. Technol. Fuels Oils, 2015, vol. 51, pp. 422–429. https://doi.org/10.1007/s10553-015-0620-y

    Article  CAS  Google Scholar 

  15. Kam’yanov, V.F., Aksenov, V.S., and Titov, V.I., Geteroatomnye komponenty nefti (Heteroatomic Components of Crude Oil), Novosibirsk: Nauka, 1983.

    Google Scholar 

  16. Nikulshin, P., Ishutenko, D., Anashkin, Yu., Mozhaev, A., and Pimerzin, A., Fuel, 2016, vol. 182, pp. 632–639. https://doi.org/10.1016/j.fuel.2016.06.016

    Article  CAS  Google Scholar 

  17. Mozhaev, A.V., Nikulshin, P.A., Pimerzin, Al.A., Maslakov, K.I., and Pimerzin, A.A., Catal. Today, 2016, vol. 271, pp. 80–90. https://doi.org/10.1016/j.cattod.2015.11.002

    Article  CAS  Google Scholar 

  18. Nikulshin, P.A., Mozhaev, A.V., Maslakov, K.I., Pimerzin, A.A., and Kogan, V.M., Appl. Catal. B, 2014, vol. 158–159, pp. 161–174. https://doi.org/10.1016/j.apcatb.2014.04.013

    Article  Google Scholar 

  19. Valyavin, G.G., Khukhrin, E.A., and Valyavin, K.G., Chem. Technol. Fuels Oils, 2007, vol. 43, pp. 191–196. https://doi.org/10.1007/s10553-007-0033-7

    Article  CAS  Google Scholar 

  20. Trejo, F., Ancheyta, J., Centeno, G., and Marroquin, G., Catal. Today, 2005, vol. 109, pp. 178–184. https://doi.org/10.1016/j.cattod.2005.08.013

    Article  CAS  Google Scholar 

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Funding

The study was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of agreement no. 14.576.21.0088 (unique agreement identifier RFMEFI57617X0088).

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Authors and Affiliations

  1. Samara State Technical University, Samara, 443100, Russia

    A. A. Sheldaisov-Meshcheryakov, P. S. Solmanov, N. M. Maximov, A. V. Mozhaev, D. I. Ishutenko, P. A. Nikul’shin & A. A. Pimerzin

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  1. A. A. Sheldaisov-Meshcheryakov
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  2. P. S. Solmanov
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  3. N. M. Maximov
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  4. A. V. Mozhaev
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  5. D. I. Ishutenko
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  6. P. A. Nikul’shin
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  7. A. A. Pimerzin
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Correspondence to N. M. Maximov.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 10, pp. 1301–1308.

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Sheldaisov-Meshcheryakov, A.A., Solmanov, P.S., Maximov, N.M. et al. Influence of the Pore Structure of a Catalyst for Demetallization of Petroleum Feedstock on the Process Results. Russ J Appl Chem 92, 1392–1398 (2019). https://doi.org/10.1134/S1070427219100094

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  • DOI: https://doi.org/10.1134/S1070427219100094

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