Skip to main content
SpringerLink
Log in

Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions

  • Catalysis
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Effect of mixed Mg–Al oxides contained in catalysts on the distribution of target products formed in cracking of a mixture of vacuum gas oil with sunflower oil was examined. It was found that the process of deoxygenation of oxygen-containing compounds can be controlled by varying the molar ratio between magnesium and aluminum in the mixed oxides. For catalyst samples containing mixed oxides with large Mg: Al molar ratios, the content of carbon dioxide in inorganic products grows, which is indicative of the increased activity of the decarboxylation reaction. In addition, the results of catalytic tests demonstrate that the highest conversion and yield of the benzine fraction are observed for catalyst samples containing mixed oxides with small magnesium-to-aluminum ratios of 0.32: 1 and 0.49: 1. A high activity of hydrogen-transfer reactions is observed for these samples, which leads to a decrease in the yield of light olefins. Thus, it is advisable, for obtaining an increased yield of C3 and C4 olefins, to include into the composition of the catalysts mixed oxides with increased content of magnesium, with Mg: Al ratios of 1.90: 1 and more.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Doronin, V.P., Sorokina, T.P., Potapenko, O.V., Lipin, P.V., Dmitriev, K.I., Korotkova, N.V., and Gur’evskikh, S.Yu., Kataliz Prom-sti, 2016, vol. 16, no. 6, pp. 71–76. https://doi.org/10.18412/1816-0387-2016-6-71-76

    Article  Google Scholar 

  2. Bobkova, T.V., Potapenko, O.V., Sorokina, T.P., and Doronin, V.P., Russ. J. Appl. Chem., 2017, vol. 90, no. 12, pp. 1900–1907. https://doi.org/10.1134/S1070427217120023.

    Article  CAS  Google Scholar 

  3. Doronin, V.P., Lipin, P.V., Potapenko, O.V., Vysotskii, V.V., Gulyaeva, T.I., and Sorokina, T.P., Catal. Ind., 2018., vol. 10, no. 4, pp. 335–343. https://doi.org/10.1134/S2070050418040050.

    Article  Google Scholar 

  4. Scherzer, J., Appl. Catal., 1991, vol. 75, no. 1, pp. 1–32. https://doi.org/10.1016/S0166-9834(00)83119-X

    Article  CAS  Google Scholar 

  5. Corma, A., Palomares, A.E., Rey, F., and Márquez, F., J. Catal., 1997, vol. 170, no. 1, pp. 140–149. https://doi.org/10.1006/jcat.1997.1750

    Article  CAS  Google Scholar 

  6. Palomares, A.E., López-Nieto, J.M., Lázaro, F.J., López, A., and Corma, A., Appl. Catal., B, 1999, vol. 20, no. 4, pp. 257–266. https://doi.org/10.1016/S0926-3373(98)00121-0

    Article  CAS  Google Scholar 

  7. Climent, M.J., Corma, A., Iborra, S., Epping, K., and Velty, A., J. Catal., 2004, vol. 225, no. 2, pp. 316–326. https://doi.org/10.1016/j.jcat.2004.04.027

    Article  CAS  Google Scholar 

  8. Polato, C.M.S., Henriques, C.A., Rodrigues, A.C.C., and Monteiro, J.L.F., Catal. Today, 2008, vol. 133–135, pp. 534–550. https://doi.org/10.1016/j.cattod.2007.12.046

    Article  Google Scholar 

  9. Wang, D., Zhang, X., Cong, X., Liu, S., and Zhou, D., Appl. Catal., A, 2018, vol. 555, pp. 36–46. https://doi.org/10.1016/j.apcata.2018.02.009

    Article  CAS  Google Scholar 

  10. Kostov, I., Mineralogiya (Metallurgy), Moscow: Mir, 1971, pp. 208–268.

    Google Scholar 

  11. Cavani, F., Trifiro, F., and Vaccari, A., Catal. Today, 1991, vol. 11, no. 2, pp. 173–301. https://doi.org/10.1016/0920-5861(91)80068-K

    Article  CAS  Google Scholar 

  12. Layered Double Hydroxides, Duan, X. and Evans, D.G., Eds., New York: Springer, 2006. Struct. Bonding, vol. 119, pp. 1–87.

    Google Scholar 

  13. Saber, O. and Tagaya, H., Rev. Adv. Mater. Sci., 2005, vol. 10, no. 1, pp. 59–63.

    CAS  Google Scholar 

  14. Melero, J.A., Clavero, M.M., Calleja, G., García, A., Miravalles, R., and Galindo, T., Energy Fuels, 2010, vol. 24, pp. 707–717. https://doi.org/10.1021/ef900914e

    Article  CAS  Google Scholar 

  15. Bielansky, P., Weinert, A., Schönberger, C., and Reichhold, A., Fuel Process. Technol., 2011, vol. 92, no. 12, pp. 2305–2311. https://doi.org/10.1016/j.fuproc.2011.07.021

    Article  CAS  Google Scholar 

  16. Doronin, V.P., Potapenko, O.V., Lipin, P.V., and Sorokina, T.P., Fuel, 2013, vol. 106, pp. 757–765. https://doi.org/10.1016/j.fuel.2012.11.027

    Article  CAS  Google Scholar 

  17. Lovás, P., Hudec, P., Hadvinová, M., and Ház, A., Fuel Process. Technol., 2015, vol. 134, pp. 223–230. https://doi.org/10.1016/j.fuproc.2015.01.038

    Article  Google Scholar 

  18. Abbasov, V., Mammadova, T., Aliyeva, N., Abbasov, M., Movsumov, N., Joshi, A., Lvov, Y., and Abdullayev, E., Fuel, 2016, vol. 181, pp. 55–63. https://doi.org/10.1016/j.fuel.2016.04.088

    Article  CAS  Google Scholar 

  19. Doronin, V.P., Lipin, P.V., Potapenko, O.V., Zhuravlev, Ya.E., and Sorokina, T.P., Khim. Interesakh Ustoich. Razvit., 2017, no. 25, pp. 385–392. https://doi.org/10.15372/khur20170404

  20. Dupain, X., Costa, D.J., Schaverien, C.J., Makkee, M., and Moulijn, J.A., Appl. Catal., B, 2007, vol. 72, nos. 1–2, pp. 44–61. https://doi.org/10.1016/j.apcatb.2006.10.005

    Article  CAS  Google Scholar 

  21. Na, J.-G., Yi, B.E., Kim, J.N., Yi, K.B., Park, S.-Y., Park, J.-H., Kim, J.-N., and Ko, C.H., Catal. Today, 2010, vol. 156, nos. 1–2, pp. 44–48. https://doi.org/10.1016/j.cattod.2009.11.008

    Article  CAS  Google Scholar 

  22. RF Patent 2 300 420 (publ. 2007).

  23. Potapenko, O.V., Doronin, V.P., Sorokina, T.P., Talsi, V.P., and Likholobov, V.A., Appl. Catal., B, 2012, vols. 117–118, pp. 177–184. https://doi.org/10.1016/j.apcatb.2012.01.014

    Article  Google Scholar 

  24. Belaya, L.A., Doronin, V.P., Sorokina, T.P., and Gulyaeva, T.I., Russ. J. Appl. Chem., 2009, vol. 82, no. 2, pp. 236–242. https://doi.org/10.1134/S1070427209020141

    Article  CAS  Google Scholar 

  25. Basila, M.R. and Kantner, T.R., J. Phys. Chem., 1966, vol. 70, no. 5, pp. 1681–1682. https://doi.org/10.1021/j100877a514

    Article  CAS  Google Scholar 

  26. Doronin, V.P. and Sorokina, T.P., Ros. Khim. Zh., 2007, vol. LI, no. 4, pp. 23–28.

    Google Scholar 

  27. Catal. Today, 1989, vol. 5, no. 1, pp. 1–120. https://doi.org/10.1016/0920-5861(89)80034-3

  28. Katikaneni, S.P.R., Adjaye, J.D., Idem, R.O., and Bakhshi, N.N., Ind. Eng. Chem. Res., 1996, vol. 35, no. 10, pp. 3332–3346. https://doi.org/10.1021/ie950740u

    Article  CAS  Google Scholar 

  29. Maher, K.D. and Bressler, D.C., Bioresour. Technol., 2007, vol. 98, no. 12, pp. 2351–2368. https://doi.org/10.1016/j.biortech.2006.10.025

    Article  CAS  PubMed  Google Scholar 

  30. Immer, J.G., Kelly, M.J., and Lamb, H.H., Appl. Catal., A, 2010, vol. 375, no. 1, pp. 134–139. https://doi.org/10.1016/j.apcata.2009.12.028

    Article  CAS  Google Scholar 

  31. Bernas, H., Eränen, K., Simakova, I., Leino, A.-R., Kordas, K., Myllyoja, J., Maki-Arvela, P., Salmi, T., and Murzin, D.Yu., Fuel, 2010, vol. 89, no. 8, pp. 2033–2039. https://doi.org/10.1016/j.fuel.2009.11.006

    Article  CAS  Google Scholar 

  32. Renz, M., Eur. J. Org. Chem., 2005, vol. 2005, no. 6, pp. 979–988. https://doi.org/10.1002/ejoc.200400546

    Article  Google Scholar 

Download references

Funding

The study was carried out und the State assignment of the Institute of Hydrocarbon Processing, Siberian Division, Russian Academy of Sciences inconformity with the Program of Basic Research of State Academies of Sciences for the years of 2013–2020 in the direction V.47, project no. V.47.1.3 [State registration number in the EGISU NIOKTR (Unified State Information System for Accounting R&D and technological activities) AAAA-A17-117021450099-9].

Author information

Authors and Affiliations

  1. Center for New Chemical Technologies, Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    P. V. Lipin, O. V. Potapenko, T. P. Sorokina & V. P. Doronin

Authors
  1. P. V. Lipin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Potapenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. P. Sorokina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. P. Doronin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. V. Lipin.

Ethics declarations

The authors state that they have no conflict of interest to be disclosed in the present communication.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 10, pp. 1291–1300.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lipin, P.V., Potapenko, O.V., Sorokina, T.P. et al. Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions. Russ J Appl Chem 92, 1383–1391 (2019). https://doi.org/10.1134/S1070427219100082

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427219100082

Keywords

Search

Navigation