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Influence of Powdered Cellulose and Charge Preparation Procedure on the Phase Composition and Characteristics of the Iron-Potassium Oxide Material

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The charge for the iron-potassium oxide system containing powdered cellulose was prepared by the sol-gel procedure and coprecipitation of salts. The influence of the charge preparation procedure, introduction of powdered cellulose, and its amount on the phase formation in the system [Fe2O3: K2O: MoO3: CeO2: CaO: TiO2: MgO: SiO2]: powdered cellulose = (100 − x) [56.71: 20.88: 11.55: 6.38: 3.68: 0.58: 0.11: 0.11]: x, where x = 0–3 wt %, on the phase formation in the system in the temperature interval 25–1200°C was studied by differential calorimetry and by thermal and X-ray diffraction analysis. The influence of the sintering conditions, introduction of powdered cellulose, and its amount on the textural characteristics of the iron-potassium oxide material was examined. The activation energies of the transformation of maghemite to hematite in the samples were calculated. The contribution of the energy released in thermal degradation of powdered cellulose to the total amount of energy was estimated. Samples of the iron-potassium oxide material with the preset phase composition and textural characteristics required for further studies of the catalytic activity were prepared.

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Acknowledgments

The authors are grateful to E.V. Tropnikov (Institute of Geology, Komi Science Center, Ural Branch, Russian Academy of Sciences) for measuring the textural characteristics of the samples.

Funding

The study was supported in part within the framework of project no. 18-3-3-31 of the Ural Branch, Russian Academy of Sciences, using the equipment of the Chemistry Center for Shared Use at the Institute of Chemistry and Geoscience Center for Shared Use at the Institute of Geology, Komi Scientific Center, Russian Academy of Sciences.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Science Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, 167982, Russia

    A. Yu. Bugaeva, I. V. Loukhina, E. G. Kazakova, L. Yu. Nazarova & Yu. I. Ryabkov

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  1. A. Yu. Bugaeva
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  2. I. V. Loukhina
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  3. E. G. Kazakova
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  4. L. Yu. Nazarova
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  5. Yu. I. Ryabkov
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Correspondence to A. Yu. Bugaeva.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 10, pp. 1271–1282.

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Bugaeva, A.Y., Loukhina, I.V., Kazakova, E.G. et al. Influence of Powdered Cellulose and Charge Preparation Procedure on the Phase Composition and Characteristics of the Iron-Potassium Oxide Material. Russ J Appl Chem 92, 1366–1376 (2019). https://doi.org/10.1134/S1070427219100069

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  • DOI: https://doi.org/10.1134/S1070427219100069

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