Skip to main content
SpringerLink
Log in

Microheterogeneous Polyetherhydroxylurethane Elastomers with Controlled Phase Structure for Structural Adhesives

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Polyetherhydroxylurethane elastomers were prepared from mixtures of epoxy urethane oligomers and diglycidyl urethane, synthesized using isophorone diisocyanate, and the properties of the products obtained were studied. Calorimetric and optical microscopic studies proved the heterogeneity of the materials obtained. These materials surpass in the strength and adhesion characteristics the analogs synthesized using toluene-2,4-diisocyanate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ling, Z., Hyun, K.J., Jeff, M., Ron, H., and Christopher, W.M., Polymer, 2007, vol. 48, pp. 6656–6667. https://doi.org/10.1016/j.polymer.2007.09.016

    Article  Google Scholar 

  2. Mekewi, M.A., Ramadan, A.M., ElDarse, F.M., Abdel Rehim, M.H., Mosa, N.A., and Ibrahim, M.A., Egypt. J. Petrol., 2017, vol. 26, no. 1, pp. 9–15. https://doi.org/10.1016/j.ejpe.2016.02.002

    Article  Google Scholar 

  3. Randall, D. and Lee, S., The Polyurethanes Book, New York: Wiley, 2003, pp. 203–285.

    Google Scholar 

  4. Prisakariu, C., Polyurethane Elastomers, from Morphology to Mechanical Aspects, Vienna: Springer, 2011, pp. 103–202.

    Book  Google Scholar 

  5. Sun, W., Yan, X., and Zhu, X., Polym. Bull., 2012, vol. 69, no. 5, pp. 621–633. https://doi.org/10.1007/s00289-012-0775-1

    Article  CAS  Google Scholar 

  6. Edwards, P.A., Striemer, G., and Webster, D.C., J. Coat. Technol. Res., 2005, vol. 2, no. 7, pp. 517–527. https://doi.org/10.1007/s11998-005-0011-0

    Article  CAS  Google Scholar 

  7. Yeganeh, H., Mehdipour-Ataei, S., and Ghaffari, M., High Perform. Polym., 2008, vol. 20, no. 2, pp. 126–145. https://doi.org/10.1177/0954008307082743

    Article  CAS  Google Scholar 

  8. Bera, M., Gupta, P., and Maji, P.K., React. Funct. Polym., 2019, vol. 139, pp. 60–74. https://doi.org/10.1016/j.reactfunctpolym.2019.03.008

    Article  CAS  Google Scholar 

  9. Patent RU 2291176, Publ. 2007.

  10. Sidorov, O.I., Milekhin, Yu.M., Matveev, A.A., Poisova, T.P., Bykova, K.A., and Sadchikov, N.V., Klei. Germet. Tekhnol., 2012, no. 9, pp. 15–21.

  11. Elchueva, A.D., Nazipov, M.M., Tabachkov, A.A., and Liakumovich, A.G., Russ. J. Appl. Chem., 2003., vol. 76, no. 3, pp. 487–490. https://doi.org/10.1023/A:1025681524423

    Article  CAS  Google Scholar 

  12. Skripinets, A.V., Danchenko, Yu.M., and Kabus’, A.V., Vost.-Evr. Zh. Pered. Tekhnol., 2015, vol. 3, no. 11, pp. 4–8.

    Google Scholar 

  13. Fedoseev, M.S., Tereshatov, V.V., and Derzhavinskaya, L.F., Russ. J. Appl. Chem., 2010, vol. 83, no. 8, pp. 1367–1371. https://doi.org/10.1134/S1070427210080070

    Article  CAS  Google Scholar 

  14. Strel’nikov, V.N., Senichev, V.Yu., Slobodinyuk, A.I., Savchuk, A.V., Volkova, E.R., Makarova, M.A., Belov, Yu.L., Derzhavinskaya, L.F., and Selivanova, D.G., Russ. J. Appl. Chem., 2018, vol. 91, no. 12, pp. 1937–1944. https://doi.org/10.1134/S1070427218120042

    Article  Google Scholar 

  15. Tereshatov, V.V., Makarova, M.A., Senichev, V.Yu., Volkova, E.R., Vnutskikh, Zh.A., and Slobodinyuk, A.I., Colloid Polym. Sci., 2015, vol. 293, no. 1, pp. 153–164. https://doi.org/10.1007/s00396-014-3395-5

    Article  CAS  Google Scholar 

  16. Valuev, V.I., Romanovskii, G.K., Safronova, T.V., and Bogatyreva, S.A., Vysokomol. Soedin., Ser. B, 1988, vol. 30, no. 5, pp. 354–356.

    CAS  Google Scholar 

  17. Li, C.Y., Chen, J.H., Chien, P.C., Chiu, W.Y., Chen, R.S., and Don, T.M., Polym. Eng. Sci., 2007, vol. 47, no. 5, pp. 625–632. https://doi.org/10.1002/pen.20734

    Article  CAS  Google Scholar 

  18. Chen, W.H., Chen, P.C., Wang, S.C., Yeh, J.T., Huang, C.Y., and Chen, K.N., J. Polym. Res., 2009, vol. 16, pp. 601–630. https://doi.org/10.1007/s10965-008-9265-4

    Article  CAS  Google Scholar 

  19. Madhavan, K. and Reddy, B.S.R., J. Polym. Sci., Part A: Polym. Chem., 2006, vol. 44, no. 9, pp. 2980–2989. https://doi.org/10.1002/pola.21401

    Article  CAS  Google Scholar 

  20. Garcia, F.G., Leyva, M.E., de Queiroz, A.A.A., and Simoes, A.Z., Int. J. Adhes. Adhes., 2011, vol. 31, no. 4, pp. 177–181. https://doi.org/10.1016/j.ijadhadh.2011.01.002

    Article  CAS  Google Scholar 

  21. Cakić, S.M., Ristić, I.S., Jašo, V.M., Radičević, R.Ž., Ilić, O.Z., and Simendić, J.K., Prog. Org. Coat., 2012, vol. 73, no. 4, pp. 415–424. https://doi.org/10.1016/j.porgcoat.2011.03.016

    Article  Google Scholar 

  22. Guadagno, L., Vertuccio, L., Sorrentino, A., Raimondo, M., Naddeo, C., Vittoria, V., Iannuzzo, G., Calv, E., and Russo, S., Carbon, 2009, vol. 47, no. 10, pp. 2419–2430. https://doi.org/10.1016/j.carbon.2009.04.035

    Article  CAS  Google Scholar 

  23. Mathew, A., Kurmvanshi, S., Mohanty, S., and Nayak, S.K., Polym. Int., 2017. https://doi.org/10.1002/pi.5412

    Article  CAS  Google Scholar 

  24. Huang, S.L. and Lai, A.J.Y., J. Membr. Sci., 1995, vol. 105, nos. 1–2, pp. 137–145. https://doi.org/10.1016/0376-7388(94)00319-T

    Article  CAS  Google Scholar 

  25. Tereshatov, V.V., Vnutskikh, Zh.A., Slobodinyuk, A.I., Makarova, M.A., and Senichev, VYu., J. Elastom. Plast., 2016, vol. 48, no. 4, pp. 289–304. https://doi.org/10.1177/0095244315576240

    Article  CAS  Google Scholar 

Download references

Funding

The study was financially supported by the Ministry of Education and Science of the Russian Federation (agreement no. 14.604.21.0192, unique project identifier RFMEFI60417X0192).

Author information

Authors and Affiliations

  1. Perm Federal Research Center, Perm, 614013, Russia

    V. N. Strel’nikov, V. Yu. Senichev, A. I. Slobodinyuk, A. V. Savchuk & E. V. Pogorel’tsev

Authors
  1. V. N. Strel’nikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Yu. Senichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Slobodinyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Savchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. V. Pogorel’tsev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. I. Slobodinyuk.

Ethics declarations

The authors declare that they have no conflict of interest.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 10, pp. 1244–1253.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Strel’nikov, V.N., Senichev, V.Y., Slobodinyuk, A.I. et al. Microheterogeneous Polyetherhydroxylurethane Elastomers with Controlled Phase Structure for Structural Adhesives. Russ J Appl Chem 92, 1342–1350 (2019). https://doi.org/10.1134/S1070427219100033

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427219100033

Keywords

Search

Navigation