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Hydro-Oxygenation of Furfural in the Presence of Ruthenium Catalysts Based on Al-HMS Mesoporous Support

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Ruthenium-containing catalyst based on an Al-HMS mesoporous aluminosilicate was synthesized, The mesoporous support and the catalyst on its basis were characterized by the methods of low-temperature desorption/adsorption of nitrogen, temperature-programmed desorption of ammonia, transmission electron microscopy, X-ray photoelectron microscopy, and energy-dispersive X-ray fluorescence analysis. The catalyst obtained was examined in the reaction of hydrodeoxygenation of the model compound of bio-oil, furfural, in the presence of water. The reaction was performed at initial hydrogen pressures of 1–7 MPa in the temperature range 200–300°C. It was shown that the catalyst under study exhibits a high activity in the hydrotransformation of furfural: the conversion was 100% in 1 h at a hydrogen pressure of 5 MPa and temperature of 200°C.

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Authors and Affiliations

  1. Moscow Lomonosov State University, Moscow, 119991, Russia

    E. A. Roldugina, N. N. Shayakhmetov, A. L. Maksimov & E. A. Karakhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    A. L. Maksimov

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  1. E. A. Roldugina
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  2. N. N. Shayakhmetov
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  3. A. L. Maksimov
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Correspondence to E. A. Roldugina.

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A co-author, A. L. Maksimov, is the Editor in Chief of Zhurnal Prikladnoi Khimii, the rest of the co-authors state that they have no conflict of interest to be disclosed in the present communication.

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 9, pp. 1214−1224.

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Roldugina, E.A., Shayakhmetov, N.N., Maksimov, A.L. et al. Hydro-Oxygenation of Furfural in the Presence of Ruthenium Catalysts Based on Al-HMS Mesoporous Support. Russ J Appl Chem 92, 1306–1315 (2019). https://doi.org/10.1134/S1070427219090167

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