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Kinetics of Butadiene Polymerization in the Presence of the TiCl4-Al(i-C4H9)3 Catalytic System Physically Modified in Turbulent Flows: Results of Computational Experiments

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The influence of the velocity of feeding the reaction mixture to a tubular turbulent diffuser-confuser apparatus and of the geometric parameters of the apparatus on the fields the flow turbulence kinetic energy and its dissipation rate was revealed in computational experiments with a model reaction, polymerization of butadiene in toluene in the presence of the TiCl4-Al(i-C4H9)3 catalytic system physically modified in turbulent flows. Correlation between the fields of the flow turbulence kinetic energy and its dissipation rate, on the one hand, and butadiene polymerization rate, on the other hand, is considered.

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Funding

The study was performed within the framework of the government assignment for the years 2017–2019 (initiative research project no. 10.5548.2017/8.9).

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Authors and Affiliations

  1. Kazan National Research Technological University, ul. Karla Marksa 68, Kazan, Tatarstan, 420015, Russia

    K. A. Tereshchenko, N. V. Ulitin, D. A. Shiyan & A. S. Ziganshina

  2. Bashkir State University, ul. Zaki Validi 32, Ufa, Bashkortostan, 450076, Russia

    V. P. Zakharov

Authors
  1. K. A. Tereshchenko
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  2. N. V. Ulitin
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  3. D. A. Shiyan
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  4. A. S. Ziganshina
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  5. V. P. Zakharov
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Corresponding author

Correspondence to N. V. Ulitin.

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Conflict of Interest

The authors declare that they have no conflict of interest.

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 9, pp. 11152–1125.

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Tereshchenko, K.A., Ulitin, N.V., Shiyan, D.A. et al. Kinetics of Butadiene Polymerization in the Presence of the TiCl4-Al(i-C4H9)3 Catalytic System Physically Modified in Turbulent Flows: Results of Computational Experiments. Russ J Appl Chem 92, 1200–1209 (2019). https://doi.org/10.1134/S1070427219090039

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  • DOI: https://doi.org/10.1134/S1070427219090039

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