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Synthesis of Polydisperse Boron Carbide and Synthesis of a Ceramic on Its Basis

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Results obtained in a study of the process of synthesis of a polydisperse boron carbide powder (average particle size 2.10 µm) characterized by a broad particle size distribution are presented. The process in which a ceramic is produced from the thus synthesized boron carbide by hot compaction was also analyzed. In some cases, a sintering additive, highly dispersed chromium carbide powder (average particle size 7.13 µm), was used. The hot compaction was performed in argon at moderate parameters: pressure 35 MPa and temperature 1950°C. The porosity and water-absorption capacity of the samples obtained are very low and do not exceed 0.02%. The average values of the bending and compression strengths were 406 and 1553 MPa, respectively. A microhardness of about 42 GPa was reached in sintering of boron carbide. The microhardness in sintering of boron carbide with addition of chromium carbide was 45–46 GPa.

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Funding

The study was supported by the Ministry of Science and Higher Education of the Russian Federation (State assignment no. 11.7662.2017/BCh).

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Authors and Affiliations

  1. Novosibirsk State Technical University, Novosibirsk, 630087, Russia

    Yu. L. Krutskii, A. N. Pel’, I. D. Kuchumova, O. E. Mats, A. G. Tyurin, Yu. Yu. Emurlaeva & S. I. Podryabinkin

  2. NANOKERAMIKS OOO, Novosibirsk, 630049, Russia

    Yu. K. Nepochatov

  3. Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    I. N. Skovorodin

  4. International Research Center on Thermal Physics and Power Engineering OOO, Novosibirsk, 630128, Russia

    K. D. Dyukova

  5. Novosibirsk State University of Architecture and Civil Engineering, Novosibirsk, 630008, Russia

    T. M. Krutskaya

Authors
  1. Yu. L. Krutskii
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  2. Yu. K. Nepochatov
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  3. A. N. Pel’
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  4. I. N. Skovorodin
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  5. K. D. Dyukova
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  6. T. M. Krutskaya
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  7. I. D. Kuchumova
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  8. O. E. Mats
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  9. A. G. Tyurin
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  10. Yu. Yu. Emurlaeva
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  11. S. I. Podryabinkin
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Corresponding author

Correspondence to Yu. L. Krutskii.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 6, pp. 719–727.

Conflict of Interest

The authors state that there is no conflict of interest to be disclosed in the present communication.

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Krutskii, Y.L., Nepochatov, Y.K., Pel’, A.N. et al. Synthesis of Polydisperse Boron Carbide and Synthesis of a Ceramic on Its Basis. Russ J Appl Chem 92, 750–758 (2019). https://doi.org/10.1134/S1070427219060041

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  • DOI: https://doi.org/10.1134/S1070427219060041

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