Russian Journal of Applied Chemistry

, Volume 92, Issue 5, pp 620–624 | Cite as

Biomass Conversion Products as Steel Corrosion Inhibitors

  • V. I. MishurovEmail author
  • E. N. Shubina
  • V. A. Klushin
  • A. A. Chizhikova
  • V. P. Kashparova
  • A. G. Berezhnaya
Applied Electrochemistry and Metal Corrosion Protection


By-products formed in the conversion of vegetable biomass (multicomponent tar) were studied in comparison with the target products of the process (5-hydroxymethylfurfural, 2,5-diformylfuran) as inhibitors of corrosion of low-carbon steel in sulfuric acid at temperatures of 25-90°C. The gravimetric method was used to determine the inhibiting effect of additives. All these additives exhibit medium protective effects in an acid medium, with the degree of protection in 1 M sulfuric acid at room temperature exceeding 80%. The potentiody-namic polarization method was used to determine the influence exerted by the additives on partial reactions of the corrosion process. It was shown that the tar and 2,5-diformylfuran behave as additives of the cathodic type, and 5-hydroxymethylfurfural, as that of a mixed type. Temperature-kinetic calculations were used to determine the mechanism of action of the inhibitors. The corrosion process occurs in the presence of additives predominantly under the kinetic control.


corrosion low-carbon steel inhibitor biomass conversion furan derivatives. capacity 


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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. I. Mishurov
    • 1
    Email author
  • E. N. Shubina
    • 1
  • V. A. Klushin
    • 2
  • A. A. Chizhikova
    • 2
  • V. P. Kashparova
    • 2
  • A. G. Berezhnaya
    • 3
  1. 1.Don State Technical UniversityRostov-on-DonRussia
  2. 2.Platov South-Russian State Polytechnic University (NPI)Novocherkassk, Rostov-on-Don oblastRussia
  3. 3.Southern Federal UniversityRostov-on-DonRussia

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