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Conductivity Studies of Glasses in the System WO3−P2O5

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Quenching method was used to obtain glasses in the system xWO3-(100-x)P2O5 (x = 70, 75, 80, 82 mol %). The electrical conductivity of the compositions was examined by a set of electrochemical techniques: impedance spectroscopy, pulse method, and dc method with different electrodes in the temperature range 25–320°C. It was shown that tungsten phosphate glasses are mostly electronic conductors possessing semiconducting properties. It was found that the electrical conductivity of the glasses grows with increasing content of tungsten oxide. The highest conductivity at room temperature (6.7 × 10-7 S cm−1) is observed for the composition 82WO3-18P2O5.

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Acknowledgments

The authors are grateful to B.D. Antonov for assistance in the X-ray diffraction analysis and to A.A. Pankratov for deposition of Pt electrodes.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620137, Russia

    S. V. Pershina

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  1. S. V. Pershina
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Correspondence to S. V. Pershina.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 4, pp. 442−449.

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Pershina, S.V. Conductivity Studies of Glasses in the System WO3−P2O5. Russ J Appl Chem 92, 482–489 (2019). https://doi.org/10.1134/S1070427219040037

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  • DOI: https://doi.org/10.1134/S1070427219040037

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