Skip to main content
Log in

Modification of Maleic Anhydride Copolymers with Aliphatic Alkylamines and Sulfanilamide

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Macromolecular amides were synthesized from copolymers of maleic anhydride with styrene or vinyl acetate and amines: ethylamine, propylamine, and sulfanilamide. As shown by pH-metry and 1H NMR, amidation of the copolymers in solution results in the formation of hemiamide and cyclic imide units for aliphatic amides, whereas in the reaction with sulfanilamide about 20 mol % of maleic anhydride units remain unchanged. Complete conversion of maleic anhydride units to hemiamide units and the formation of maleimide units are reached in the mechanochemical reaction of the copolymer with sulfanilamide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Popescu, I., Suflet, D.M., Pelin, I.M., and Chiţanu, G.Ch., Rev. Roum. Chim., 2011, vol. 56, no. 3, pp. 173–188.

    CAS  Google Scholar 

  2. Vilara, G., Tulla-Puchea, J., and Albericio, F., Curr. Drug Deliv., 2012, vol. 9, no. 4, pp. 1–28.

    Google Scholar 

  3. Henry, S.M., El-Sayed, M.E.H., Pirie, Ch.M., Hoffman, A.S., and Stayton, P.S., Biomacromolecules, 2006, vol. 7, pp. 2407–2414.

    Article  CAS  PubMed  Google Scholar 

  4. Rajput, R.S. and Singh, A., Int. J. Chem Tech Res., 2014, vol. 6, no. 1, pp. 391–399.

    Google Scholar 

  5. Plessis, A., Functionalized Polymer Nanofibrous Substrates as Capturing Platforms for Mycobacteria, MSc Dissertation, Stellenbosch, 2016.

    Google Scholar 

  6. Moghadam, P.N., Azaryan, E., and Zeynizade, B., J. Macromol. Sci. A: Pure Appl. Chem., 2010, vol. 47, no. 8, pp. 839–848.

    Article  CAS  Google Scholar 

  7. Rodriguez, V.B., Henry, S.M., Hoffman, A.S., Stayton, P.S., Li, X., and Pun, S.H., J. Biomed. Opt., 2008, vol. 13, no. 1, pp. 014025–1–10.

    Article  CAS  PubMed  Google Scholar 

  8. Sauvage, E., Amos, D.A., Antalek, B., Schroeder, K.M., Tan, J.S., Plucktaveesak, N., and Colby, R.H., J. Polym. Sci. B: Polym. Phys., 2004, vol. 42, pp. 3571–3583.

    Article  CAS  Google Scholar 

  9. Rajput, R.S., Rupainwar, D.C., and Singh, A., Int. J. ChemTech Res., 2009, vol. 31, no. 4, pp. 915–919.

    Google Scholar 

  10. Sun, C.X., van der Mee, M.A.J., Goossens, J.G.P., and van Duin, M., Macromolecules, 2006, vol. 39, no. 9, pp. 3441–3449.

    Article  CAS  Google Scholar 

  11. Spectral Database for Organic Compounds. http://www.sdbs.db.aist.go.jp/sdbs/cgi-bin/cre_index.cgi. Cited July 2, 2018.

  12. Mpitso, K., Synthesis and Characterization of Styrene-Maleic Anhydride Copolymer Derivatives, MSc Dissertation, Stellenbosch, 2009.

    Google Scholar 

  13. Zhao, E., Lam, J.W.Y., Meng, L., Hong, Y., Deng, H., Bai, G., Huang, X., Hao, J., and Tang, B.Z., Macromolecules, 2015, vol. 48, no. 1, pp. 64–71.

    Article  CAS  Google Scholar 

  14. Boldyrev, V.V., Russ. Chem. Rev., 2006, vol. 75, no. 3, pp. 177–189.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. G. Tyurina.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tyurina, T.G., Kryuk, T.V. Modification of Maleic Anhydride Copolymers with Aliphatic Alkylamines and Sulfanilamide. Russ J Appl Chem 92, 351–359 (2019). https://doi.org/10.1134/S1070427219030054

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427219030054

Keywords

Navigation