Skip to main content
SpringerLink
Log in

Pervaporation Membranes Based on Interpolyelectrolyte Complexes of an Aromatic Copolyamide Containing Sulfonate and Carboxy Groups

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Film membranes were prepared from interpolyelectrolyte complexes of various aliphatic polyamines with a copolyamide synthesized from isophthalic dichloride and two diamines: disodium 4,4′-diaminobiphenyl-2,2′-disulfonate and 4,4′-diaminodiphenylmethane-2,2′-dicarboxylic acid. The mechanical and sorption properties of the membranes and their performance in pervaporation separation of the water-isopropanol mixture were studied. The possibility of thermal cross-linking of the materials was demonstrated. The effect of the amidation on the physicochemical and mass-exchange properties of the film samples was examined. The variation of the separation characteristics of the membranes depending on the copolyamide composition was considered. With respect to the combination of separation and transport properties, the interpolymer systems containing the copolyimide with low (7 mol %) content of units with carboxy groups are of most interest. An increase in the fraction of carboxyl-containing units in the polyanion leads to an increase in the permeability of the materials with a significant decrease in their selectivity. The tensile strength of the film samples prepared from copolyamide-containing interpolyelectrolyte complexes is 54–92 MPa.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Thünemann, A.F., Müller, M., Dautzenberg, H., Joanny, J.-F., and Löwen, H., Adv. Polym. Sci., 2004, vol. 166, pp. 113–171.

    Article  CAS  Google Scholar 

  2. Kabanov, V.A., Russ. Chem. Rev., 2005, vol. 74, no. 1, pp. 3–20.

    Article  CAS  Google Scholar 

  3. Polyelectrolyte Complexes in the Dispersed and Solid State. I. Principles and Theory, Müller, M., Ed., Berlin: Springer, 2014.

    Google Scholar 

  4. Multilayer Thin Films: Sequential Assembly of Nanocomposite Materials, Decher, G. and Schlenoff, J., Eds., Weinheim: Wiley-VCH, 2003.

    Google Scholar 

  5. Polyelectrolyte Complexes in the Dispersed and Solid State. II. Application Aspects, Müller, M., Ed., Berlin: Springer, 2014.

    Google Scholar 

  6. Advances in Biomaterials for Biomedical Applications, Tripathi, A. and Melo, J.S., Eds., Singapore: Springer, 2017.

    Google Scholar 

  7. Membrane Hydration: the Role of Water in the Structure and Function of Biological Membranes, Disalvo, E.A., Ed., New York: Springer, 2015.

    Google Scholar 

  8. Permeability of Biological Membranes, Banfalvi, G., Ed., Switzerland: Springer, 2016.

    Google Scholar 

  9. Zhumadilova, G.T., Gazizov, A.D., Bimendina, L.A., and Kudaibergenov, S.E., Polymer, 2001, vol. 42, pp. 2985–2989.

    Article  CAS  Google Scholar 

  10. Oliveira, H.C.L., Fonseca, J L.C., and Pereira, M.R., J. Biomater. Sci. Polym. Ed., 2008, vol. 19, no. 2, pp. 143–160.

    Article  PubMed  Google Scholar 

  11. Jin, H., An, Q.-F., Zhao, Q., Qian, J., and Zhu, M., J. Membr. Sci., 2010, vol. 347, pp. 183–192.

    Article  CAS  Google Scholar 

  12. Xu, J., Gao, C., and Feng, X., J. Membr. Sci., 2010, vol. 352, pp. 197–204.

    Article  CAS  Google Scholar 

  13. Zhao, Q., An, Q.F., Ji, Y., Qian, J., and Gao, C., J. Membr. Sci., 2011, vol. 379, pp. 19–45.

    Article  CAS  Google Scholar 

  14. Li, Y., Jia, H., Cheng, Q., Pan, F., and Jiang, Z., J. Membr. Sci., 2011, vol. 375, pp. 304–312.

    Article  CAS  Google Scholar 

  15. Han, G.L., Gong, Y., Zhang, Q.G., Zhu, A., Ye, M.L., and Liu, Q.L., J. Membr. Sci., 2013, vol. 447, pp. 246–252.

    Article  CAS  Google Scholar 

  16. Wang, X.-S., An, Q.-F., Liu, T., Zhao, Q., Hung, W.-S., Lee, K.-R., and Gao, C.-J., J. Membr. Sci., 2014, vol. 452, pp. 73–81.

    Article  CAS  Google Scholar 

  17. Joseph, N., Ahmadiannamini, P., Hoogenboom, R., and Vankelecom, I.F.J., Polym. Chem., 2014, vol. 5, pp. 1817–1831.

    Article  CAS  Google Scholar 

  18. Petrova, V.A., Orekhov, A.S., Chernyakov, D.D., Baklagina, Yu.G., Romanov, D.P., Kononova, S.V., Volod’ko, A.V., Ermak, M., Klechkovskaya, V.V., and Skorik, Yu.A., Crystallogr. Rep., 2016, vol. 61, no. 6, pp. 945–953.

    Article  CAS  Google Scholar 

  19. Kirsh, Yu.E., Vdovin, P.A., Fedotov, Yu.A., Platonov, K.N., Smirnova, N.N., Zemlyakova, O.Yu., and Timashev, S.F., Polym. Sci., Ser. B, 1997, vol. 39, nos. 5–6, pp. 189–193.

    Google Scholar 

  20. Smirnova, N.N. and Fedotov, Yu.A., Membrany, 2004, no. 1 (21), pp. 29–34.

    Google Scholar 

  21. Kirsh, Yu.E., Vdovin, P.A., Fedotov, Yu.A., Semenova, S.I., Platonov, K.N., and Timashev, S.F., Polym. Sci., Ser. A, 1996, vol. 38, no. 2, pp. 330–334.

    CAS  Google Scholar 

  22. Smirnova, N.N., Russ. J. Appl. Chem., 2018, vol. 91, no. 3, pp. 404–411.

    Article  CAS  Google Scholar 

  23. Smirnova, N.N. and Volkov, V.I., Russ. J. Appl. Chem., 2015, vol. 88, no. 3, pp. 480–487.

    Article  CAS  Google Scholar 

  24. Bernabé, P., Peniche, C., and Argüelles-Monal, W., Polym. Bull., 2005, vol. 55, pp. 367–375.

    Article  CAS  Google Scholar 

  25. Fedotov, Yu.A., Il’in, M.I., Gitis, S.S., Subbotin, V.A., and Valgin, S.V., Vysokomol. Soedin., Ser. B, 1995, vol. 37, no. 11, pp. 1929–1931.

    CAS  Google Scholar 

  26. Kirsh, Yu.E. and Timashev, S.F., Membrany, 1999, no. 1, pp. 15–46.

    Google Scholar 

  27. Timashev, S.F. and Gladkikh, S.N., Dokl. Akad. Nauk SSSR, 1982, vol. 262, no. 3, pp. 656–661.

    CAS  Google Scholar 

  28. Kirsh, Yu.E., Vysokomol. Soedin., Ser. A, 1993, vol. 35, no. 3, pp. 163–170.

    CAS  Google Scholar 

  29. Volkov, V.I., Pavlov, A.A., Fedotov, Yu.A., and Marinin, A.A., Russ. J. Phys. Chem. A, 2010, vol. 84, no. 10, pp. 1705–1711.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Stoletovy State University, Vladimir, 600000, Russia

    N. N. Smirnova

Authors
  1. N. N. Smirnova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. N. Smirnova.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Smirnova, N.N. Pervaporation Membranes Based on Interpolyelectrolyte Complexes of an Aromatic Copolyamide Containing Sulfonate and Carboxy Groups. Russ J Appl Chem 92, 222–227 (2019). https://doi.org/10.1134/S1070427219020083

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427219020083

Keywords

Search

Navigation