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Extractive Recovery and Separation of Palladium(II) from Model Hydrochloric Solution from Refining Shop with Di-n-Heptyl Sulfide and Penconazole

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Extractive method for recovery of palladium(II) from a model palladium-rich hydrochloric solution from a refining shop was suggested. It was found that palladium(II) is fully extracted with di-n-heptyl sulfide and penconazole from 3 M hydrochloric solutions with high salt background, with the optimal phase contact duration being 20 and 5 min, respectively. As reagent dilutions served toluene and chloroform. Palladium(II) was back-extracted with a 15% aqueous ammonia and a saturated aqueous solution of sodium rhodanide. The optimal conditions of palladium(II) extraction and its separation from the accompanying platinum(IV) and copper(II).

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Acknowledgments

The study was carried out under the State assignment “Complexation of mono- and polydentate sulfur-and-nitrogen-containing organic compounds with metal ions and pharmacons” no. AAAA-A17-117011910033-1.

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Authors and Affiliations

  1. Ufa Institute of Chemistry—Subdivision of the Ufa Federal Research Centre, Russian Academy of Sciences, Ufa, Bashkortostan, 450054, Russia

    R. A. Khisamutdinov, L. G. Golubyatnikova & Yu. I. Murinov

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  1. R. A. Khisamutdinov
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  2. L. G. Golubyatnikova
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  3. Yu. I. Murinov
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Correspondence to R. A. Khisamutdinov.

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Khisamutdinov, R.A., Golubyatnikova, L.G. & Murinov, Y.I. Extractive Recovery and Separation of Palladium(II) from Model Hydrochloric Solution from Refining Shop with Di-n-Heptyl Sulfide and Penconazole. Russ J Appl Chem 92, 31–34 (2019). https://doi.org/10.1134/S107042721901004X

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  • DOI: https://doi.org/10.1134/S107042721901004X

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