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Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts

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Abstract

Comparative studies of oxidative transformations of ethane and ethylene were performed on multi-component oxide catalysts of the preset cationic composition, V0.3Mo1Te0.23Nb0.12, differing in the final calcination temperature. The highest (∼74%) ethylene yield in oxidative dehydrogenation of ethane is reached on the catalysts calcined in the temperature interval 550–650°C, which is due to the formation of the maximal amount of the active M1 phase.

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References

  1. Xie, Q., Chen, L.Q., Weng, W.Z., and Wan, H.L., J. Mol. Catal. A, 2005, vol. 240, pp. 191–196.

    CAS  Google Scholar 

  2. Finashina, E.D., Kucherov, A.V., and Kustov, L.M., Russ. J. Phys. Chem. A, 2013, vol. 87, pp. 1983–1988.

    Article  CAS  Google Scholar 

  3. Chieregato, A., López Nieto, J.M., and Cavani, F., Coord. Chem. Rev., 2015, vols. 301–302, pp. 3–23.

    Article  CAS  Google Scholar 

  4. Cavani, F., Ballarini, N., and Cericola, A., Catal. Today, 2007, vol. 127, pp. 113–131.

    Article  CAS  Google Scholar 

  5. Solsona, B., Vazquez, M.I., Ivars, F., Dejoz, A., Concepción, P., and López Nieto, J.M., J. Catal., 2007, vol. 252, pp. 271–280.

    Article  CAS  Google Scholar 

  6. López Nieto, J.M., Top. Catal., 2006, vol. 41, pp. 3–15.

    Article  CAS  Google Scholar 

  7. Quintana-Solorzano, R., Barragan-Rodriguez, G., Armendariz-Herrera, H., López-Nieto, J.M., and Valente, J.S., Fuel, 2014, vol. 138, pp. 15–26.

    Article  CAS  Google Scholar 

  8. López Nieto, J.M., Botella, P., Vázquers, M.I., and Dejoz, A., Chem. Commun., 2002, pp. 1906–1907.

    Google Scholar 

  9. Patent RU 26004555, Publ. 2015.

  10. DeSanto, P., Buttrey, D.J., Grasselli, R.K., Lugmair, C.G., Volpe, A.F., Toby, B.H., and Vogt, Th., Z. Kristallogr., 2004, vol. 219, pp. 152–165.

    CAS  Google Scholar 

  11. Holmberg, J., Grasselli, R.K., and Andersson, A., Appl. Catal. A, 2004, vol. 270, pp. 121–134.

    Article  CAS  Google Scholar 

  12. DeSanto, P., Buttrey, D.J., Grasselli, R.K., Lugmair, C.G., Volpe, A.F., Toby, B.H., and Vogt, Th., Top. Catal., 2003, vol. 23, pp. 23–38.

    Article  CAS  Google Scholar 

  13. Bondareva, V.M., Ishchenko, E.V., Shadrina, L.A., and Sobolev, V.I., Katal. Prom-sti., 2015, no. 6, pp. 36–38.

    Google Scholar 

  14. Grasselly, R.K., Burrindton, J.D., Buttrey, D.J., De-Santo, P., Jr., Lugmaird, C.G., Volpe, A.F., Jr., and Weingand, Th., Top. Catal., 2003, vol. 23, pp. 5–22.

    Article  Google Scholar 

  15. Lin, M.M., Appl. Catal. A, 2003, vol. 250, pp. 287–303.

    Article  CAS  Google Scholar 

  16. Oliver, J.M., Lopez Nieto, J.M., Botella, P., and Mifsud, A., Appl. Catal. A, 2004, vol. 257, pp. 67–76.

    Article  CAS  Google Scholar 

  17. Beato, P., Blume, A., Girgsdise, F., Jentoft, R.E., Schlögl, R., Timpe, O., Trunschke, A., Weinberg, G., Basher, Q., Hamid, F.A., Hamid, S.B.A., Omar, E., and Mohd Salim, L., Appl. Catal. A, 2006, vol. 307, pp. 137–147.

    Article  CAS  Google Scholar 

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Correspondence to V. M. Bondareva.

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Bondareva, V.M., Lazareva, E.V., Kardash, T.Y. et al. Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts. Russ J Appl Chem 92, 122–127 (2019). https://doi.org/10.1134/S10704272190100178

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  • DOI: https://doi.org/10.1134/S10704272190100178

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