Abstract
Flowsheets based on the results of experimental studies and detailed kinetic modeling were suggested for oxidative cracking of oil refinery gas components to obtain ethylene, CO, and hydrogen. The calculations show that oxidative cracking alone does not allow production of ethylene and СО in ratios required for the further catalytic carbonylation and hydroformylation of ethylene. Matrix conversion of a part of oxy-cracking products is suggested as an additional step for producing CO and hydrogen.
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Original Russian Text © A.V. Ozerskii, A.V. Nikitin, I.V. Sedov, I.G. Fokin, V.I. Savchenko, V.S. Arutyunov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 12, pp. 1790−1800.
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Ozerskii, A.V., Nikitin, A.V., Sedov, I.V. et al. Production of Ethylene, CO, and Hydrogen by Oxidative Cracking of Oil Refinery Gas Components. Russ J Appl Chem 91, 2065–2075 (2018). https://doi.org/10.1134/S1070427218120200
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DOI: https://doi.org/10.1134/S1070427218120200