Abstract
Development of novel corrosion inhibitors is important for improving the anticorrosion of carbon steel because the serious carbon steel corrosion causes enormous economic losses to humankind. In this work, we demonstrated the novel organic functionalized Fe3O4 hybrid inhibitor for enhancing the anticorrosion performance of carbon steel. For this purpose, amino-Fe3O4 nano-spheres (NH2–Fe3O4) were prepared via solvothermal route, using FeCl3.6H2O as an iron source and 3-aminophenoxy-phthalonitrile as precursor. Then, the N,N-diethyl-3-amine methyl propionate (DM) was reacted with amino-Fe3O4 nano-spheres to produce the organic functionalized nano-Fe3O4 hybrid. The chemical composition and micro-structure of as-obtained organic functionalized Fe3O4 hybrid were characterized and confirmed by Fourier transform infrared, X-ray diffraction, and scanning electron microscopy. Furthermore, the anticorrosion performance of carbon steel by addition of organic functionalized nano-Fe3O4 inhibitor was investigated by AC impedance measurements and polarization curves. The research results showed that the organic functionalized nano-Fe3O4 exhibited enhanced inhibition effect for carbon steel, which can be used as a new type of carbon steel corrosion inhibitor.
Similar content being viewed by others
References
Raps, D., Hack, T., Wehr, J., Zheludkevich, M.L., Bastos, A.C., Ferreira, M.G.S., and Nuyken, O., Corros. Sci. 2009, vol. 51, pp. 1012–1021.
El-Mahdy, G.A., Atta, A.M., and Al-Lohedan, H.A., J. Taiwan Inst. Chem. E, 2014, vol. 45, no. 4, pp. 1947–1953.
Singh, H.K., Yeole, K.V., and Mhaske, S.T., Chem. Eng. J. 2016, vol. 295, pp. 414–426.
Asri, N.F., Husaini, T., Sulong, A.B., Majlan, E.H., and Wan, R.W.D., Int. J. Hydrogen Energ. 2017, vol. 42, no. 14, pp. 9135–9148.
Mourya, P., Banerjee, S., and Singh, M., Corros. Sci. 2014, vol. 85, pp. 352–363.
Yüce, A.O., Mert, B.D., Kardaş, G., and Yazıcı, B., Corros. Sci. 2014, vol. 83, pp. 310–316.
Gupta, M., Mishra, J., and Pitre, K., Int. J. Corros. 2013, vol. 2013, pp. 1–5.
Li, G.L., Schenderlein, M., Men, Y., Möhwald, H., and Shchukin, D.G., Adv. Mater. Interfaces 2014, vol. 1, pp. 1300019.
Zhu, W., Li, W.F., Mu, S.L., Fu, N.Q., and Liao, Z.M., Appl. Surf. Sci. 2017, vol. 405, pp. 157–168.
Deflorian, F., Rossi, S., Fedel, M., and Motte, C., Prog. Org. Coat. 2010, vol. 69, no. 2, pp. 158–166.
Zhan, Y.Q., Zhang, J.M., Wan, X.Y., Long, Z.H., He, S.J., and He, Y., Appl. Sur. Sci., 2018, Vol, 436, pp. 756–767.
Gao, H., Yuan, Q.Z., Zhu, X.F., Zhao, Y.P., and Liu, M.H., Langmuir 2012, vol. 28, no. 43, pp. 15410–15417.
Mohammed, A.A., Corros. Sci. 2010, vol. 52, no. 10, pp. 3243–3257.
Aramki, K., Corros. Sci., 2002, vol. 44, no. 4, pp.871–886.
Blin, F., Leary, S.G., Wilson, K., Deacon, G.B., Junk, P.C., and Forsyth, M., J. Appl. Electrochem., 2004, vol. 34, no. 6, pp. 591–599.
Martin-Gallego, M., Verdejo, R., Lopez-Manchado, M.A., and Sangermano, M., Polymer, 2011, vol. 52, pp.4664–4669.
Potts, J.R., Dreyer, D.R., Bielawski, C.W., and Ruoff, R.S., Polymer 2011, vol. 52, pp. 5–25.
Zhan, Y.Q., Wan, X.Y., He, S.J., Yang, Q.B., and He, Y., Chem. Eng. J. 2018, vol. 333, pp. 132–145.
Aiguo, Hu G.T.Y. and Lin, W.B., J. Am. Chem. Soc. 2005, vol. 127, pp. 12486–12487.
Wang, P.Q.S., Shi, Y.F., Clark, K.K., Stucky, G.D., and Keller, A.A., J. Am. Chem. Soc., 2008, vol. 131, pp. 182–188.
Hu, P.L.Y., Zuo, A.H., Guo, C.Y., and Yuan, F.L., J. Phys. Chem. C, 2009, vol. 2009, pp. 900–906.
Wan, X., Zhan, Y., Long, Z., Zeng, G., Ren, Y., and He, Y., Appl. Sur. Sci. 2017, vol. 425, pp. 905–914.
Wan, X., Zhan, Y., Long, Z., Zeng, G., and He, Y., Chem. Eng. J. 2017, vol. 330, pp. 491–504.
Wan, X.Y., Zhan, Y.Q., Zeng, G.Y., and He, Y., Appl. Sur. Sci. 2017, vol. 393, pp. 1–10.
Zhan, Y.Q., Hu, H., He, Y., Long, Z.H., Wan, X.Y., and Zeng, G.Y., Russ. J. Appl. Chem. 2016, vol. 89, no. 11, pp. 1894–1902.
Wan, J.Q., Cai, W., Feng, J.T., Meng, X.X., and Liu, E.Z., J. Mater. Chem., 2007, vol. 17, p. 1188.
Zhan, Y.Q., Wan, X.Y., Long, Z.H., Fan, Y., and He, Y., Russ. J. Appl. Chem. 2016, vol. 89, no. 2, pp. 297–303.
Kosari, A., Moayed, M.H., Davoodi, A., Parvizi, R., Momeni, M., Eshghi, H., and Moradi, H., Corros. Sci. 2014, vol. 78, pp. 138–150.
Author information
Authors and Affiliations
Corresponding author
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Zhan, Y., Zhao, R., He, S. et al. Organic Functionalized Nano-Fe3O4 Hybrid Inhibitor for Enhancing the Anticorrosion Performance of Carbon Steel. Russ J Appl Chem 91, 2058–2064 (2018). https://doi.org/10.1134/S1070427218120194
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427218120194