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Evaluation of the Hydrodesulfurization Activity in Development of Catalysts for Demetallization of Heavy Petroleum Feedstock

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Abstract

Efficiency of various compositions of demetallization catalysts was studied in hydrodesulfurization of heavy crude oil. It was shown that the highest activity is observed for trimetallic NiCoMo systems, including those prepared with the use of heteropoly compounds. The influence exerted by introduction of up to 3 wt % ultrastable zeolite Y into the demetallization catalyst support on the activity in hydrodesulfurization reactions was examined. It was shown that addition of this zeolite makes it possible to reduce the content of sulfur in the reaction products, compared with the alumina support, and to preserve a high activity on raising the space velocity of feed.

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Authors and Affiliations

  1. All-Russia Research Institute of Oil Refining, Moscow, 111116, Russia

    R. E. Boldushevskii, A. I. Guseva, N. Ya. Vinogradova & P. A. Nikul’shin

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    E. R. Naranov & A. L. Maksimov

Authors
  1. R. E. Boldushevskii
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  2. A. I. Guseva
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  3. N. Ya. Vinogradova
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  4. E. R. Naranov
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  5. A. L. Maksimov
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  6. P. A. Nikul’shin
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Corresponding author

Correspondence to R. E. Boldushevskii.

Additional information

Original Russian Text © R.E. Boldushevskii, A.I. Guseva, N.Ya. Vinogradova, E.R. Naranov, A.L. Maksimov, P.A. Nikul’shin, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 12, pp. 1784−1789.

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Boldushevskii, R.E., Guseva, A.I., Vinogradova, N.Y. et al. Evaluation of the Hydrodesulfurization Activity in Development of Catalysts for Demetallization of Heavy Petroleum Feedstock. Russ J Appl Chem 91, 2046–2051 (2018). https://doi.org/10.1134/S1070427218120170

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  • DOI: https://doi.org/10.1134/S1070427218120170

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