Abstract
NiMo/γ-Al2O3 protective-layer catalysts for removing silicon from diesel fractions were examined. The catalysts differ in the way in which boron is introduced into the support. The supports and catalysts were examined by X-ray diffraction analysis, transmission electron microscopy, IR spectroscopy, and adsorption–desorption of nitrogen. The catalysts were tested in hydropurification of the diesel fraction to which decamethylcyclopentanesiloxane was added as a model silicon compound. It was shown that introduction of boron into the support results in that the surface area of the supports and catalysts increases. If boron is introduced into pseudoboehmite, massive particles of the Ni–Mo–S phase are formed. It was found that the highest capacity for silicon is observed for the catalyst into which boron is introduced in the stage of pseudoboehmite preparation.
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Dubreuil, A.-C., Chainet, F., de Sousa Bartolomeu, R.M., Mota, F.M.M., Janvier, J., and Lienemann, C.-P., Compt. Rend. Chim. 2017, vol. 20, no. 1, pp. 55–66.
Pérez-Romo, P., Aguilar-Barrera, C., Navarrete-Bo laños, J., Rodríguez-Otal, L.M., Beltrán, F.H., and Fripiat, J., Appl. Catal., A, 2012, vol. 449, pp. 183–187.
Pérez-Romo, P., Navarrete-Bolaños, J., Aguilar-Barrera, C., Angeles-Chavez, C., and Laredo, G.C., Appl. Catal., A 2014, vol. 485, pp. 84–90.
Ismagilov, Z.R., Shkrabina, R.A., and Koryabkina, N.A., Alyumooksidnye nositeli: proizvodstvo, svoistva i primenenie v kataliticheskikh protsessakh zashchity okruzhayushchei sredy. Analiticheskii obzor (Aluminum oxide supports: manufacture, properties, and application in catalytic processes for environment protection. Analytical review), Novosibirsk: Gos. Publ. Nauch.-Tekh. Bibl. Sib. Otd. Ross. Akad. Nauk, 1998.
Vatutina, Y., Klimov, O.V., Nadeina, K.A., Danilo va, I.G., Gerasimov, E.Y., Prosvirin, I.P., and Noskov, A.S., Appl. Catal., B, 2016, vol. 199, pp. 23–32.
Torres-Mancera, P., Ramírez, J., Cuevas, R., Gutiérrez- Alejandre, A., Murrieta, F., and Luna, R., Catal. Today, 2005, vols. 107–108, pp. 551–558.
Chen, W., Maugé, F., van Gestel, J., Nie, H., Li, D., and Long, X., J. Catal. (Academic Press), 2013, vol. 304, pp. 47–62.
Dhar, G.M., Srinivas, B., Rana, M., Kumar, M., and Maity, S., Catal. Today 2003, vol. 86, nos. 1–4, pp. 45–60.
de Farias, A.M.D., Esteves, A.M.L., Ziarelli, F., Caldarelli, S., Fraga, M.A., and Appel, L.G., Appl. Surf. Sci. 2004, vol. 227, nos. 1–4, pp. 132–138.
Bautista, F.M., Campelo, J.M., Garcia, A., Luna, D., Marinas, J.M., Moreno, M.C., and Romero, A.A., J. Catal., 1998, vol. 173, no. 2, pp. 333–344.
Ding, L., Zhang, Z., Zheng, Y., Ring, Z., and Chen, J., Appl. Catal., A 2006, vol. 301, no. 2, pp. 241–250.
Usman Kubota, T., Hiromitsu, I., and Okamoto, Y., J. Catal., 2007, vol. 247, no. 1, pp. 78–85.
Danilevich, V.V., Lakhmostov, V.S., Zakharov, V.P., Tanashev, Yu.Yu., Sokolov, D.N., Isupova, L.A., and Parmon, V.N., Katal. Prom–sti 2016, vol. 16, no. 1, pp. 13–28.
Danilevich, V.V., Klimov, O.V., Nadeina, K.A., Gerasimov, E.Y., Cherepanova, S.V., Vatutina, Y.V., and Noskov, A.S., Superlattices Microstruct. 2018, vol. 120, pp. 148–160.
Klimov, O.V., Pashigreva, A.V., Leonova, K.A., Bukh tiyarova, G.A., Budukva, S.V., and Noskov, A.S., Stud. Surf. Sci. Catal., 2010, vol. 175, pp. 509–512.
Karpova, T.R., Buluchevskii, E.A., Lavrenov, A.V., Leont’eva, N.N., Trenikhin, M.V., Gulyaeva, T.I., and Talzi, V.P., Khim. Interesakh Ustoich. Razvit. 2013, vol. 21, pp. 61–68.
Lavrenov, A.., Buluchevskii, E.A., Karpova, T.R., Moiseenko, M.A., Mikhailova, M.S., Chumachenko, Yu.A., Skorplyuk, A.A., Gulyaeva, T.I., Arbuzov, A.B., Leont’eva, N.N., and Drozdov, V.A., Khim. Interesakh Ustoich. Razvit. 2011, vol. 19, pp. 87–95.
Dubois, J.-L. and Fujieda, S., Stud. Surf. Sci. Catal. 1995, vol. 91, pp. 833–842.
Busca, G., Lorenzelli, V., Ramis, G., and Willey, R., Langmuir 1993, vol. 9, no. 6, pp. 1492–1499.
Morterra, C. and Magnacca, G., Catal. Today 1996, vol. 27, no. 3, pp. 497–532.
Low, M.J.D. and Ramasubramanian, N., J. Phys. Chem., 1966, vol. 70, pp. 2740–2746.
Delmastro, A., Gozzelino, G., Mazza, D., Vallino, M., Busca, G., and Lorenzelli, V., J. Chem. Soc., Faraday Trans. 1992, vol. 88, pp. 2065–2070.
Thommes, M., Kaneko, K., Neimark, A., Olivier, J., Rodriguez-Reinoso, F., Rouquerol, J., and Sing, K., Pure Appl. Chem. 2015, vol. 87, pp. 1051–1069.
Chainet, F., Meur, L., Courtiade, M., Lienemann, C.P., and Ponthus, J., Fuel 2014, vol. 116, pp. 478–489.
Chainet, F., Meur, L., Courtiade, M., Lienemann, C.P., and Ponthus, J., Fuel 2013, vol. 111, pp. 519–527.
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Original Russian Text © A.A. Koval’skaya, K.A. Nadeina, M.O. Kazakov, V.V. Danilevich, I.G. Danilova, E.Yu. Gerasimov, O.V. Klimov, A.S. Noskov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 12, pp. 1760−1767.
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Koval’skaya, A.A., Nadeina, K.A., Kazakov, M.O. et al. Effect of Method of Boron Introduction into NiMo/Al2O3 Protective-Layer Catalysts on the Removal of Silicon from Diesel Fractions. Russ J Appl Chem 91, 2022–2029 (2018). https://doi.org/10.1134/S1070427218120145
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DOI: https://doi.org/10.1134/S1070427218120145