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Use of Vanadium-Containing Slime for Preparing Cathodes for Lithium-Ion Current Sources

  • Applied Electrochemistry and Metal Corrosion Protection
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Abstract

Crude vanadium-containing dump slimes can be used as a raw material for preparing lithium vanadium oxides suitable as cathode materials for lithium-ion chemical current sources. A simple procedure for preparing LiV3O8 from the slime was suggested. The synthesized compound was characterized by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and synchronous thermal analysis. The material prepared from vanadium-containing dump slimes has uniform microstructure and high electronic conductivity of the order of 1.4 × 10–2 S cm–1; it is thermally stable in the interval 30–550°С and capable of intercalation/deintercalation of lithium ions in its structure in the course of cycling in lithium-ion current sources.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    M. S. Shchelkanova, G. Sh. Shekhtman & A. A. Pankratov

Authors
  1. M. S. Shchelkanova
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  2. G. Sh. Shekhtman
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  3. A. A. Pankratov
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Correspondence to M. S. Shchelkanova.

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Original Russian Text © M.S. Shchelkanova, G.Sh. Shekhtman, A.A. Pankratov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 11, pp. 1595−1601.

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Shchelkanova, M.S., Shekhtman, G.S. & Pankratov, A.A. Use of Vanadium-Containing Slime for Preparing Cathodes for Lithium-Ion Current Sources. Russ J Appl Chem 91, 1799–1804 (2018). https://doi.org/10.1134/S1070427218110095

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  • DOI: https://doi.org/10.1134/S1070427218110095

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