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Effect of 1-Butanol on the Contrast of Photopolymerizing Compounds Based on Dimethacrylate Esters

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The kinetics of visible-light-induced photopolymerization of dimethacrylate derived from phthalic acid, oligo(carbonate dimethacrylate), and triethylene glycol dimethacrylate (MDF-2, OKM-2, and TGM-3, respectively) in the bulk and in the presence of 10–30 wt % 1-butanol and of 9,10-phenanthrenequinone as initiator was studied. The illuminance in the reaction zone was varied from 10 to 40 klx. Introduction of 10 wt % 1-butanol into dimethacrylates of grades MDF-2 and OKM-2 does not alter their photopolymerization kinetics, and a further increase in the alcohol concentration leads to a decrease in the photopolymerization rate. Addition of 10 wt % and larger amounts of 1-butanol to dimethacrylate of grade TGM-3 makes the dependence of the photopolymerization rate at 1% monomer conversion and of the time of reaching 1% monomer conversion on the actinic radiation intensity considerably more pronounced.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, 603950, Russia

    M. Yu. Zakharina, Yu. V. Chechet, N. Yu. Shushunova, S. A. Chesnokov & G. A. Abakumov

Authors
  1. M. Yu. Zakharina
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  2. Yu. V. Chechet
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  3. N. Yu. Shushunova
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  4. S. A. Chesnokov
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  5. G. A. Abakumov
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Corresponding author

Correspondence to S. A. Chesnokov.

Additional information

Original Russian Text © M.Yu. Zakharina, Yu.V. Chechet, N.Yu. Shushunova, S.A. Chesnokov, G.A. Abakumov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 11, pp. 1540−1548.

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Zakharina, M.Y., Chechet, Y.V., Shushunova, N.Y. et al. Effect of 1-Butanol on the Contrast of Photopolymerizing Compounds Based on Dimethacrylate Esters. Russ J Appl Chem 91, 1750–1757 (2018). https://doi.org/10.1134/S1070427218110034

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  • DOI: https://doi.org/10.1134/S1070427218110034

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