Skip to main content
Log in

Smart Coating Based on Urea-Formaldehyde Microcapsules Loaded with Benzotriazole for Corrosion Protection of Mild Steel in 3.5 % NaCl

  • Applied Electrochemistry and Metal Corrosion Protection
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Urea-formaldehyde (UF) microcapsules loaded with linseed oil (LO) and benzotriazole (BTA) as core materials have been synthesized by in situ emulsion polymerization. The capsules were characterized by FTIR spectroscopy and particle size analysis. Surface morphology of the microcapsules was analyzed using scanning electron microscopy (SEM). The microcapsules were incorporated into epoxy resin and coated on a mild steel substrate to form a corrosion resistant organic coating. The self-healing property of coatings loaded with different weight % of microcapsules containing LO + BTA was tested by immersion of the UF coated mild steel specimens in 3.5 wt % NaCl solution. It was analyzed through visual inspection, weight loss measurements, and SEM of the scribed region of coating. It was observed that the addition of microcapsules enhances the corrosion resistance of the scratched samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Eduok, U., Suleiman, R., Khaled, M., and Akid, R., Prog. Org. Coat., 2016, vol. 93, pp. 97–108.

    Article  CAS  Google Scholar 

  2. Suleiman, R., Dafalla, H., and El Ali, B., RSC Adv., 2015, vol. 5 (49), pp. 39155–39167.

    Article  CAS  Google Scholar 

  3. Kumar, A.M. and Gasem, Z.M., Prog. Org. Coat., 2015, vol. 78, pp. 387–394.

    Article  CAS  Google Scholar 

  4. Kumar, A.M. and Gasem, Z.M., Surf. Coat. Technol., 2015, vol. 276, pp. 416–423.

    Article  CAS  Google Scholar 

  5. Kumar, A.M., Rahman, M.M., and Gasem Z.M., RSC Adv., 2015, vol. 5(78), pp. 63537–63544.

    Article  Google Scholar 

  6. Siva, T., Kamaraj, K., and Sathiyanarayanan, S., Progress in Organic Coatings, 2014, vol. 77, pp. 1095–1103.

    Article  CAS  Google Scholar 

  7. Siva, T. and Sathiyanarayanan, S., Prog. Org. Coat., 2015, vol. 82, pp. 57–67.

    Article  CAS  Google Scholar 

  8. Siva, T., Mayavan, S., Sreejakumari, S.S., and Sathiyanarayanan, S., RSC Adv., 2015, vol. 5, pp. 39278–39284.

    Article  CAS  Google Scholar 

  9. Kamaraj, K., Devarapalli, R., Siva, T., and Sathiyanarayanan, S., Mater. Chem. Phys., 2015, vol. 153, pp. 256–265.

    Article  CAS  Google Scholar 

  10. Falcóna, J.M., Batista, F.F., and Aokia, I.V., Electrochim. Acta, 2014, vol. 124, pp. 109–118.

    Article  CAS  Google Scholar 

  11. Huang, M., Zhang, H., and Yang, J., Corros. Sci., 2012, vol. 65, pp. 561–566.

    Article  CAS  Google Scholar 

  12. White, S.R., Sottos, N.R., Geubelle, P.H., Morre, J.S., Kessler, M.R., Sriram, S.R., Brown, E.N., and Viswanathan, S., Nature, 2001, vol. 409, pp. 794–797.

    Article  CAS  PubMed  Google Scholar 

  13. Cho, S.H., White, S.R., and Braun, P.V., Adv. Mater., 2009, vol. 21, pp. 645–649.

    Article  CAS  Google Scholar 

  14. Blaiszik, B.J., Kramer, S.L.B., Olugebefola, S.C., Moore, J.S., Sottos, N.R., and White, S.R., Annu. Rev. Mater. Res., 2010, 40, pp. 179–211.

    Article  CAS  Google Scholar 

  15. Wu, D.Y., Meure, S., and Solomon, D., Prog. Polym. Sci., 2008, vol. 33, pp. 479–522.

    Article  CAS  Google Scholar 

  16. Wool, R.P., Soft Matter., 2008, vol. 4, pp. 400–418.

    Article  CAS  PubMed  Google Scholar 

  17. Kessler, M.R., Proc. IMechE, Part G: J. Aerospace Engineering, 2007, vol. 221, pp. 478–494.

    Google Scholar 

  18. Williams, K.A., Dreyer, D.R., and Bielawski, C.W., MRS Bulletin, 2008, vol. 33, pp. 759–765.

    Article  CAS  Google Scholar 

  19. Boura, S.H., Peikari, M., Ashrafi, A., and Samadzadeh, M., Prog. Org. Coat., 2012, vol. 75, pp. 292–300.

    Article  CAS  Google Scholar 

  20. Suryanarayanaa, C., Chowdoji Raob, K., and Dhirendra Kumar, Prog. Org. Coat., 2008, vol. 63, pp. 72–78.

    Article  CAS  Google Scholar 

  21. Behzadnasab, M., Mirabedini, S.M., Esfandeh, M., and Farnood, R.R., Prog. Org. Coat., 2017, vol. 105, pp. 212–224.

    Article  CAS  Google Scholar 

  22. Gite, V.V., Tatiya, P.D., Marathe, R.J., Mahulikar, P.P., and Hundiwale, D.G., Prog. Org. Coat., 2015, vol. 83, pp. 11–18.

    Article  CAS  Google Scholar 

  23. Marathe, R.J., Chaudhari, A.B., Hedaoo, R.K., Sohn, D., Chaudhari, V.R., and Gite, V.V., RSC Adv., 2015, vol. 5, pp. 15539–15546.

    Article  CAS  Google Scholar 

  24. Siva, T., Kamaraj, K., and Sathiyanarayanan, S., Prog. Org. Coat., 2014, vol. 77, pp. 1095–1103.

    Article  CAS  Google Scholar 

  25. Jin, H., Miller, G., Pety, S., Griffin, A., Stradley, D., Roach, D., Sottos, N., and White, S., Int. J. Adhes. Adhes., 2013, vol. 44, pp. 157–165.

    Article  CAS  Google Scholar 

  26. Pratama, P., Shari, M., Peterson A., and Palmese, G., ACS Appl. Mater. Interfaces, 2013, vol. 5, pp. 12425–12431.

    Article  CAS  PubMed  Google Scholar 

  27. Verma, C., Olasunkanmi, L.O., Ebenso, E.E., Quraishi, M.A., and Obot, I.B., J. Phys. Chem. C, 2016, vol. 120, pp. 11598–11611.

    Article  CAS  Google Scholar 

  28. Singh, P., Ebenso, E.E., Olasunkanmi, L.O., Obot, I.B., and Quraishi, M.A., J. Phys. Chem. C, 2016, vol. 120, pp. 3408–3419.

    Article  CAS  Google Scholar 

  29. Ansari, K.R., and Quraishi, Singh, A., Corros. Sci., 2015, vol. 95, pp. 62–70.

    Article  CAS  Google Scholar 

  30. Fan, C., Tang, J.T., and Zhou, X.D., J. Appl. Polym. Sci., 2013, vol. 129, pp. 2848–2856.

    Article  CAS  Google Scholar 

  31. Fan, C. and Zhou, X., Polym. Bull., 2011, vol. 67, pp. 15–27.

    Article  CAS  Google Scholar 

  32. Thanawala, K., Mutneja, N., Khanna, A.S., and Raman, R.K.S., Materials, 2014, vol. 7, pp. 7324–7338.

    Article  PubMed  PubMed Central  Google Scholar 

  33. Brown, E.N., Kessler, M.R., Sottos, N.R., and White, S.R., J. Microencapsulation, 2003, vol. 20, pp. 719–730.

    Article  CAS  PubMed  Google Scholar 

  34. Miguel, M.D.L.P., Ollier, R., Alvarez, V., and Vallo, C., Prog. Org. Coat., 2016, vol. 97, pp. 194–202.

    Article  CAS  Google Scholar 

  35. Huang, M. and Yang, J., J. Mater. Chem., 2011, vol. 21, pp. 11123–11130.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. A. Quraishi.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fadil, M., Chauhan, D.S. & Quraishi, M.A. Smart Coating Based on Urea-Formaldehyde Microcapsules Loaded with Benzotriazole for Corrosion Protection of Mild Steel in 3.5 % NaCl. Russ J Appl Chem 91, 1721–1728 (2018). https://doi.org/10.1134/S107042721810021X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107042721810021X

Keywords

Navigation